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    Chapter

    Dioxygen Ligand Transfer from Platinum to Molybdenum. Isolation of a Highly Reactive Molybdenum(VI) Oxoperoxo Dimer

    The reaction of Pt(O2)(PPh3)2 with Mo(O)2(mesityl)2 (mesityl = 2,4,6-Me3C6H2) in pyridine results in the transfer of the dioxygen ligand from platinum to molybdenum giving, in the presence of PPh4CI, a molybdenum...

    H. Arzoumanian, J. Sanchez, G. Strukul in The Activation of Dioxygen and Homogeneous… (1993)

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    Chapter

    Enantioselective Lactonization of Cyclic Ketones with H2O2 Catalyzed by Complexes of Platinum(II)

    The Baeyer-Villiger oxidation of ketones to give esters is an oxygen transfer reaction typical of organic peroxy acids. We have recently reported that this reaction can be easily accomplished with hydrogen per...

    G. Strukul, A. Gusso, F. Pinna in The Activation of Dioxygen and Homogeneous… (1993)