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    Book

    Catalytic Reductive Carbonylation of Organic Nitro Compounds

    Sergio Cenini, Fabio Ragaini in Catalysis by Metal Complexes (1997)

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    Chapter

    Synthesis of Other Non-Cyclic Compounds

    Nitroalkanes have been rarely used as substrates for catalytic reactions with carbon monoxide. This is mainly due to the fact that they usually react with transition metal complexes in their aci form [1]. Thus...

    Sergio Cenini… in Catalytic Reductive Carbonylation of Organic Nitro Compounds (1997)

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    Chapter

    Mechanistic Studies

    Despite some effort, the detailed mechanism of most of the reactions described in this book is still poorly understood. The main reason for this lack of knowledge is the fact that almost all of the catalytic p...

    Sergio Cenini… in Catalytic Reductive Carbonylation of Organic Nitro Compounds (1997)

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    Chapter

    Introduction

    A number of modern industrial processes are based on the catalytic carbonylation of organic substrates by carbon monoxide [1–4]. Important chemicals incorporating carbon monoxide, such as oxo alcohols, acetic ...

    Sergio Cenini… in Catalytic Reductive Carbonylation of Organic Nitro Compounds (1997)

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    Chapter

    Synthesis of Carbamates and Ureas

    In the previous chapter, we have discussed the catalytic systems leading to the direct synthesis of isocyanates. However, these processes are all plagued by insufficient selectivities, mainly due to self-conde...

    Sergio Cenini… in Catalytic Reductive Carbonylation of Organic Nitro Compounds (1997)

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    Chapter

    Synthesis of Heterocycles

    The synthesis of carbamates and isocyanates via the catalytic carbonylation of organic nitro compounds (Chapters 2 and 3) is still not competitive with respect to the classical phosgene route. However, this is tr...

    Sergio Cenini… in Catalytic Reductive Carbonylation of Organic Nitro Compounds (1997)

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    Chapter

    Synthesis of Isocyanates

    The interaction of carbon monoxide with organic nitro compounds is a thermodynamically highly favourable process. For reaction (1): 1 % MathType!MTEF!2!1!+- % feaagCart1ev2aaatCvAUfe...

    Sergio Cenini… in Catalytic Reductive Carbonylation of Organic Nitro Compounds (1997)