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Article
In Situ Structure Study of a TiO2 Doped MnOX-Na2WO4/SiO2 Catalyst Under Na2WO4 Melting Conditions
MnOX-Na2WO4/SiO2 catalyst exhibited notable C2 selectivity/yield in the oxidative coupling of methane (OCM), a promised green chemistry reaction. Nevertheless, the reaction mechanism of this catalyst remains a su...
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Article
Sulfur Poisoning and Regeneration Behavior of Perovskite-Based NO Oxidation Catalysts
SO x uptake and release properties of LaMnO3, Pd/LaMnO3, LaCoO3 and Pd/LaCoO3 perovskites were investigated via in situ Fourier transform infrared (FTIR) spectroscopy, temperatu...
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Article
Photocatalytic Activity of Mesoporous Graphitic Carbon Nitride (mpg-C3N4) Towards Organic Chromophores Under UV and VIS Light Illumination
A template-assisted synthetic method including the thermal polycondensation of guanidine hydrochloride (GndCl) was utilized to synthesize highly-organized mesoporous graphitic carbon nitride (mpg-C3N4) photocatal...
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Article
Comparative Analysis of Reactant and Product Adsorption Energies in the Selective Oxidative Coupling of Alcohols to Esters on Au(111)
Gold-based heterogeneous catalysts have attracted significant attention due to their selective partial oxidation capabilities, providing promising alternatives for the traditional industrial homogeneous cataly...
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Article
NaCl-Promoted CuO–RuO2/SiO2 Catalysts for Propylene Epoxidation with O2 at Atmospheric Pressures: A Combinatorial Micro-reactor Study
A combinatorial approach is used to investigate several alkali metals promoted Cu–Ru binary oxide catalysts with improved catalytic performance in the propylene partial oxidation. 2 %Cu/5 %Ru/c–SiO2 catalyst had ...
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Article
In-Situ Vibrational Spectroscopic Studies on Model Catalyst Surfaces at Elevated Pressures
Elucidation of complex heterogeneous catalytic mechanisms at the molecular level is a challenging task due to the complex electronic structure and the topology of catalyst surfaces. Heterogeneous catalyst surf...
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Article
Enhanced Sulfur Tolerance of Ceria-Promoted NO x Storage Reduction (NSR) Catalysts: Sulfur Uptake, Thermal Regeneration and Reduction with H2(g)
SO x uptake, thermal regeneration and the reduction of SO x via H2(g) over ceria-promoted NSR catalysts were investigated. Sulfur poisoning an...