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Article
Preparing High-Octane Motor Fuel Components via the Oxidation of an Industrial Isobutane Fraction
The deep processing of heavy oil increases the production of hydrocarbon gases. The resulting butanes do not always find an equivalent market. A mixture of oxygenates with a high octane number is obtained in t...
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Article
Hydrodeoxygenation of methyl-substituted ketones using the composite loading of hydrogenation and dehydration catalysts
The hydrogenation/hydrodeoxygenation of methyl-substituted carbonyl compounds to preserve the isomeric structure of a product is one way of controlling its amount of oxygen and improving the chemical stability...
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Article
New methods for the preparation of high-octane components from catalytic cracking olefins
A new method has been suggested for the preparation of high-octane components from the butane–butylene fraction (BBF) in two stages. At the first stage, the BBF olefins are oxidized with N2O into carbonyl compoun...
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Article
Phenol oxidation by nitrous oxide: The role of zeolite catalyst acidity
Gas-phase phenol oxidation using nitrous oxide on zeolite catalysts is of great interest as an alternative method of dihydroxybenzene (DHB) synthesis. Catalysts for conducting this reaction with high selectivi...
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Article
Phenol hydroxylation with nitrous oxide
Phenol hydroxylation with nitrous oxide opens up a new, promising way to the gas-phase synthesis of dihydroxybenzenes, which are among the most important semiproducts of contemporary organic chemistry. A proce...
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Article
Mechanism of Coke Influence on the Catalytic Activity of FeZSM-5 in the Reaction of Benzene Oxidation into Phenol
The influence of coke formation in the reaction of benzene oxidation by nitrous oxide into phenol on the catalytic activity and concentration of iron-containing active sites (α-sites), which are stabilized in ...