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Article
DOUBLE YTTRIUM THIOSILICATES AYSiS4 (A = Rb, Cs): SYNTHESIS, STRUCTURE, OPTICAL PROPERTIES
By the high-temperature synthesis new double yttrium thiosilicates AYSiS4, A = Rb, Cs are obtained. The compounds crystallize in the orthorhombic system (space group P212121) with the following parameters: a = 6....
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Article
The mechanism of allyl isomerization of unsaturated compounds catalyzed by organomagnesium clusters
The paper presents a density functional theory investigation of the mechanism of allyl isomerization of olefins on magnesium clusters for the example of the Mg4-allylbenzene system. The rearrangement of the clust...
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Article
Catalytic isomerization of allylbenzene on organomagnesium clusters
Catalytic isomerization of allylbenzene to form trans-β-methylstyrene quantitatively occurs on the magnesium-anthracene cluster adduct under mild conditions. A low-stability organomagnesium compound, presumably o...
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Article
Catalytic Self-Hydrogenation of Anthracene in the Presence of a Magnesium–Anthracene Adduct
The catalytic properties of cluster magnesium derivatives were studied using the self-hydrogenation reaction of unsaturated compounds as an example. In the presence of a cluster magnesium–anthracene adduct at ...