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Reference Work Entry In depth
Conversion of Lignin into High Value Chemical Products
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Article
Addendum: Aldehydes as alkyl carbanion equivalents for additions to carbonyl compounds
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Article
Aldehydes as alkyl carbanion equivalents for additions to carbonyl compounds
Nucleophilic addition reactions of organometallic reagents to carbonyl compounds for carbon–carbon bond construction have played a pivotal role in modern chemistry. However, this reaction's reliance on petrole...
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Article
Photo-induced iodination of aryl halides under very mild conditions
Aryl iodides are useful precursors in the synthesis of compounds used, for example, in the pharmaceutical and electronics industries. This protocol describes a transition metal–free, photo-induced aromatic Fin...
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Chapter
Catalytic Grignard-Type Addition of Aryl C‐H Bonds to C=O and C=N Bonds
As an alternative to the classical Grignard reaction, transition-metal catalyzed direct addition of aryl C-H bonds to carbonyl groups and their analogues have recently attracted increasing attention due to its...
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Chapter
Cross-Dehydrogenative Coupling Reactions of sp3-Hybridized C–H Bonds
New methodologies in cross-coupling reaction using C–H bonds as substrates is of great interest due to the challenges associated with C–H bond activation and the potential to streamline synthesis by the elimin...
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Article
A chiral conjugated oligomer based on 1,1′-binaphthol with 3,3′-acetylene spacer
A 1,1′-binaphthol based optically active oligomer 6 with 3,3′-acetylene spacer was prepared from 2,2′-dimethoxy-1,1′-binaphthalene 3 through the palladium-catalyzed Stille coupling reaction. The high optical r...