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Article
Open AccessAcceptorless cross-dehydrogenative coupling for C(sp3)-H heteroarylation mediated by a heterogeneous GaN/ketone photocatalyst/photosensitizer system
Alkanes are naturally abundant chemical building blocks that contain plentiful C(sp3)-H bonds. While inert, the activation of C(sp3)-H via hydrogen atom abstraction (HAT) stages an appealing approach to generate ...
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Article
Iodomethane as an organocatalyst for the aerobic ortho-selective trifluoromethylation of pyridines
Iodomethane is usually used as an electrophilic methylation reagent. Herein, we report its use as a C1 organocatalyst for the aerobic ortho-selective trifluoromethylation of pyridines in the absence of a trans...
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Article
A Cu/Cinchona P,N-ligand system enabled general asymmetric C(sp3)-C(sp) coupling
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Article
Open AccessCatalytic N-modification of α-amino acids and small peptides with phenol under bio-compatible conditions
The functionalization of α-amino acids and peptides provides the opportunity to tailor the properties of these biomolecules for diverse applications in chemistry and biology. Previous methods for N-modification i...
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Living Reference Work Entry In depth
Conversion of Lignin into High Value Chemical Products
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Article
Addendum: Aldehydes as alkyl carbanion equivalents for additions to carbonyl compounds
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Article
Aldehydes as alkyl carbanion equivalents for additions to carbonyl compounds
Nucleophilic addition reactions of organometallic reagents to carbonyl compounds for carbon–carbon bond construction have played a pivotal role in modern chemistry. However, this reaction's reliance on petrole...
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Article
Ru(II)-catalyzed ortho-amidation and decarboxylation of aromatic acids: a versatile route to meta-substituted N-aryl benzamides
Carboxylate as a promising and valuable directing group has attracted a great deal of attention. However, employing it as a traceless direction group has rarely been reported. We developed the ruthenium-cataly...
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Article
Unorthodox chemistry for an unorthodox challenge: Exploration of new chemical reactivities for a sustainable future
The sustainable development of our future represents an unorthodox challenge in sciences and technologies. The exploration of unconventional chemical reactivities that could potentially result in more sustaina...