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Article
Magnesia–Carbon Nanotubes (MgO–CNTs) Nanocomposite: Novel Support of Ru Catalyst for the Generation of COx-Free Hydrogen from Ammonia
Magnesia–carbon nanotubes (abbreviated as MgO–CNTs) nanocomposites were prepared by impregnation of CNTs with Mg(NO3)2·6H2O in ethanol solution, followed by drying at 353 K and calcination at 873 K, respectively....
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Article
Catalytic Production of Carbon Nanotubes by Decomposition of CH4 over the Pre-reduced Catalysts LaNiO3, La4Ni3O10, La3Ni2O7 and La2NiO4
A large amount of more graphitic carbon nanotubes with a narrow size distribution was produced from catalytic decomposition of CH4 over pre-reduced LaNiO3, La4Ni3O10, La3Ni2O7 and La2NiO4. The structure and compo...
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Article
Halogenated La1.6Sr.04CuO4 catalysts active for ethane selective oxidation to ethene
The catalytic performances and characterization of the catalysts La1.6Sr0.4CuO3.852, La1.6Sr0.4CuO3.857F0.143, and La1.6Sr0.4 CuO3.856Cl0.126 have been investigated for the oxidative dehydrogenation of ethane (OD...
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Article
Mechanistic studies of CO2/CH4 reforming over Ni–La2O2/5A
The mechanism of CO2/CH4 reforming over Ni–La2O3/5A has been studied. The results of the CO2‐pulsing experiments indicated that the amount of CO2 converted was roughly proportional to the amount of H present on t...
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Article
The catalytic performance and characterization of a durable perovskite-type chloro-oxide SrFeO3–δClσ catalyst selective for the oxidative dehydrogenation of ethane
The catalytic performances and properties of SrFeO3-0.190 and SrFeO3-0.382Cl0.443 catalysts have been investigated for the oxidative dehydrogenation of ethane (ODE). XRD results showed that both catalysts exhibit...
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Article
An ab initio study of methane activation on lanthanide oxide
Ab initio MP2 calculations have been carried out to study the activation of methane on lanthanide oxide La2O3. O- and O2 2- are assumed to be the active species on the oxide surface. The p...
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Article
Oxidative coupling of methane over LaF3/La2O3 catalysts
We studied the oxidative coupling of methane over the LaF3/La2O3 (50∶50) catalyst. The catalyst was found active even at 873 K. At 1023 K, the C2 yield was 12.7% at 26.0% CH4 conversion and 49.1% C2 selectivity. ...