-
Article
Manufacture of Granulated Chitosan
Conditions for dry-wet spinning of spherical chitosan granules 0.5–2.0 mm in diameter into a two-layer spinning bath consisting of immiscible liquids are proposed, where an organic liquid, decane in particular...
-
Article
Synthesis and physicochemical study of NiII complexes with tetradentate acyclic and macrocyclic N2S2 ligands as thiosalen analogs
N,N’-Polymethylenebis(thiosalicylidene)iminate and macrocyclic dithiadiazadibenzocycloalkadiene complexes of nickel(II) were synthesized and their electrochemical and spectroscopic properties were studied. Dithi...
-
Article
One-pot process in phosphonium-iodonium ylides: nucleophilic substitution and the Wittig reaction
The nucleophilic substitution in mixed phosphonium-iodonium ylides was investigated. The iodonium group is replaced by such S-containing nucleophiles as the thiocyanate anion or thiourea, as well as by halide ...
-
Article
Initiated pseudo-[3+2] cycloaddition of mixed phosphonium-iodonium ylides to acetonitrile
-
Article
Structure determination of bis{(4Z)-1-(2-azidoethyl)-4-[(pyridin-2-yl)methylidene]-2-thiolatoimidazol-5(4H)-one}dicopper chloride from X-ray powder diffraction data
The new tridentate organic N2S-type ligand, (4Z)-1-(2-azidoethyl)-4-[(pyridin-2-yl)-methylidene]-2-thioxoimidazol-5(4H)-one (LH), was synthesized. The reaction of LH with copper(II) chloride in a CH2Cl2/MeOH mixt...
-
Article
Synthesis, structure, and properties of Schiff base iodobismuthate and its alteration in DMSO solution
New hybrid iodobismuthates (C12H18N2)(BiI4)2 (1, C12H18N2 is N,N´-bis(1- methylethylidene)-1,4-benzоdiammonium dication) and (C6H4(NH3)2) [Bi2I8•2DMSO]•4DMSO (2, C6H4(NH3)2 is p-phenylenediammonium dication) were...
-
Article
Mixed iodonium-, phosphonium-, arsonium-, sulfoniumdiazonium ylides in reactions with nucleophiles
The reactions of mixed ylides containing a diazonium fragment and an "onium" group of different nature with nucleophiles were studied. In the iodonium-diazonium and sulfoniumdiazonium ylide, the nucleophile fi...
-
Article
A novel structural type of conformationally fixed, mixed phosphonium-iodonium ylides based on phenoxaphosphinine
A synthetic approach to a novel type of phosphonium and mixed phosphonium-iodonium ylides containing a conformationally fixed phosphonium fragment is developed. New representatives of these families of chemica...
-
Article
Mathematical Modelling of Friction Winding of Large-Dia Meter Packages on a Translationally Moving Hanger
The article considers the problem of develo** a dynamic and mathematical model of a receivingwinding mechanism for producing large-diameter packages. In the mechanism, the bobbin holder with the package rota...
-
Article
Regioselective heterocyclization of mixed phosphonium-iodonium ylides with acetylenes involving dimethyl acetylenedicarboxylate
A new approach to the synthesis of λ5-phosphinolines was developed consisting in the reaction of mixed phosphonium-iodonium ylides with acetylenes in the presence of dimethyl acetylenedicarboxylate as a dipolarop...