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Article
A Quantum-Chemical Study of Tautomeric Equilibria of Fluorescein Dyes in DMSO
We evaluated the relative thermodynamic stability of various molecular and anionic tautomers of fluorescein, its 2,4,5,7-tetrabromo derivative (eosin), and also sulfofluorescein, 4'- and 5'-amino-fluoresceins,...
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Article
Implementation of the Results of Mathematical Modeling of Orientation of Polypropylene Fibre
Process schemes for implementation of the optimum conditions of the final stage of orientational drawing of PP fibre are proposed based on the results of mathematical modeling. The existence of successive stag...
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Article
Analysis and Optimization of the Concluding Stage of Orientation of Polypropylene Fibre
An algorithm and system for mathematical modeling and optimization of the concluding stage of orientation of PP fibre are proposed. The adequacy of the mathematical model was confirmed in different drawing reg...
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Article
Mathematical Model of the Final Stage of Orientation of Polypropylene Fibre
A mathematical model of the final stage of orientation of polypropylene fibre is constructed. The stress of the polymer in the hyperelastic state is used as an indirect estimation of the orientation index. A r...
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Article
Analysis of the Change in Relaxation Properties of Polypropylene Fibre in Deformation
A method is proposed for analyzing the change in the relaxation parameters of polymers during deformation by the method of repeated drawing with holding at each step until relaxation occurs. It is shown that t...
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Article
Formalization of the Problem of Optimum Control of the Mechanical Properties of Polypropylene Fibre
The problem was examined and a system was proposed for optimization of industrial fabrication of chemical fibres using relaxation parameters as indirect evaluation of the structure of the polymer. The necessit...