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Article
Simple chiral sulfinyl imine–thioether ligands for Pd-catalyzed allylic alkylation
A set of chiral sulfinyl imine–thioether ligands are prepared via dehydration condensation of substituted benzaldehyde and chiral sulfinamide. The activity of these ligands in Pd-catalyzed asymmetric allylic a...
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Article
Structure and properties of gel-spun ultra-high molecular weight polyethylene fibers with high gel solution concentration
The gel-spun ultra-high molecular weight polyethylene (UHMWPE) fibers were prepared at the industrial production line with different gel solution concentrations of 15 wt%, 18 wt% and 24 wt%. The difference in ...
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Article
The influence of chitin nanocrystals on structural evolution of ultra-high molecular weight polyethylene/chitin nanocrystal fibers in hot-drawing process
Ultra-high molecular weight polyethylene (UHMWPE)/chitin nanocrystal (CNC) fibers were prepared. Compared with the pure UHMWPE fibers, the ultimate tensile strength and Young’s modulus of UHMWPE/CNC fibers are...
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Article
Tuning the bridging modes of Cu-azido complexes with Schiff bases by varying the terminal groups
Three azido-bridged copper(II) complexes, [Cu2(L1)2(μ1,1,3-N3)2] n ·2nH2O (1), [Cu4(L2)4(μ1,1-N3)2(μ1,1,3-N3)2] n (2), and [Cu2(L3)2(μ1,1-N3)2]...
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Article
Synthesis, Characterization and Crystal Structure of a Mononuclear Zinc(II) Complex Derived from 2-[(2-Propylaminoethylimino)methyl]phenol
A new zinc(II) complex, [Zn(C12H18N2O)Cl2]·CH3CN, derived from the Schiff base ligand 2-[(2-propylaminoethylimino)methyl]phenol, has been synthesized and characterized by elemental analysis, IR spectra, and X-ray...
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Article
Synthesis, crystal structures and xanthine oxidase inhibitory activities of two copper(II) complexes with Schiff bases
Two azido-coordinated Schiff base Cu(II) complexes with the formulae [Cu(L1)(N3)]·MeOH and [Cu(L2)(μ1,1-N3)] n , where L1 is the deprotonated form of 2-chloro-2-[(2-ethylaminoeth...
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Article
Crystal structure of 25,27-bis[(2-cyanophenyl)methoxy] calix[4]arene
The crystal structure of 25,27-bis[(2-cyanophenyl)methoxy] calix[4]arene (C44H34N2O4) was determined by X-ray crystallographic analysis. It possesses space group R