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104 Result(s)
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Article
A new [SiMo12O40]4−-based metal organic framework: synthesis, structure, photo-/electro-catalytic and absorption properties
The water pollution problems caused by organic dyes, inorganic ions and other pollutants are becoming more and more serious, and the removal of pollutants from wastewater is still a challenge. A polyoxometalat...
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Article
Spatiotemporal and global profiling of DNA–protein interactions enables discovery of low-affinity transcription factors
Precise dissection of DNA–protein interactions is essential for elucidating the recognition basis, dynamics and gene regulation mechanism. However, global profiling of weak and dynamic DNA–protein interactions...
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Article
Zinc loaded amidoxime polyacrylonitrile porous resin microcapsules for uranium extraction from seawater
In this study, a microcapsule resin grafted with amidoxime group was prepared by phase transformation method, and the microcapsule resin was loaded with zinc as an antibacterial agent. The final preparation of...
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Article
Preparation of porous amidoximated nanofibers with antibacterial properties, and experiments on uranium extraction from seawater
A novel porous adsorbent, named silver-loaded amidoximated polyacrylonitrile porous nanofibers (Ag@AO-PAN PNF), with both adsorption and antibacterial properties, was designed and synthesized by using polyviny...
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Article
A three-dimensional Pb-centered coordination framework: crystal structure and electrochemiluminescent property
Rigid, dicarboxylic acid ligand 5-(4-carboxyphenyl)-1H-pyrazole-3-carboxylic acid (H3L) has been synthesized and utilized for assembling a metal organic framework [Pb2(HL)2]n through the hydrothermal technique. T...
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Article
Norbornene polymerization and copolymerization with ethylene by titanium complexes bearing pyridinium imide ligand
A novel titanium complex was synthesized and characterized, and its catalytic behavior for the homopolymerization of norbornene (NB) and copolymerization with ethylene (E) was investigated. After activation wi...
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Article
Polyvinylpyrrolidone-assisted aqueous synthesis of monodisperse CH3NH3PbBr3 perovskite nanocrystals
Metal halide perovskites are difficult to be prepared entirely in water due to their ionic nature. Aqueous synthesis routes of methylammonium lead bromide (CH3NH3PbBr3) perovskite were reported previously, but th...
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Article
Three coordination polymers of manganese(II), cadmium(II) with a flexible ligand of cis, cis, cis-1,2,3,4-cyclopentanetetracarboxylic acid: crystal structures, thermal decomposition mechanisms and magnetic properties
The synthesized condition by means of controlling pH values of the reaction mixtures has been explored. Three Mn2+, Cd2+ ion coordination polymers with the fully deprotonated cis, cis, cis-1,2,3,4-cyclopentanetet...
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Article
Mechanism-based ligand design for copper-catalysed enantioconvergent C(sp3)–C(sp) cross-coupling of tertiary electrophiles with alkynes
In contrast with the well-established enantioconvergent radical C(sp3)–C cross-coupling of racemic secondary alkyl electrophiles, the corresponding coupling of tertiary electrophiles to forge all-carbon quaternar...
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Article
Fabrication of Gallic Acid Loaded SeNPs and their Neuroprotection Effect for Treatment of Ischemic Stroke
Ischemic stroke (IS) is a usual cerebrovascular ailment having high mortality and morbidity globally. The approaches for the treatment and prevention of cerebral ischemia–reperfusion injury (CIRI) are very lim...
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Article
Porous nanofiber membrane from phase separation electronspun for selectively recovering uranium from seawater
Polymer fibers with amidoxime group are promising candidates to extract uranium from seawater. However, their application is limited majorly by small specific surface area. Here, we show a facial method by jus...
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Article
SnSe nanoparticles with the ultra-low lattice thermal conductivity: synthesis and characterization
Tin selenide (SnSe) with an orthorhombic system has recently become a hot spot in the thermoelectric field owing to its low thermal conductivity and high melting point. In this work, P-type SnSe nanoparticles ...
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Article
Rationalizing the catalytic performance of Cr(III) complexes stabilized with alkylphosphanyl PNP ligands for selective ethylene tri-/tetramerization: a DFT study
The effect of alkylphosphanyl substitutions on the PNP scaffold toward ethylene tri-/tetramerization has been explained using density functional theory (DFT). Our calculations show that different alkylphosphan...
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Article
A study on the clearance of metal frames of waste filters from ventilation system in nuclear power plant
The ventilation filters from ventilation system in the control area of nuclear power plant will be regularly replaced. In general, the metal frame of the waste filters would not be activated and were expected ...
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Article
A directive Ni catalyst overrides conventional site selectivity in pyridine C–H alkenylation
Achieving the transition metal-catalysed pyridine C3−H alkenylation, with pyridine as the limiting reagent, has remained a long-standing challenge. Previously, we disclosed that the use of strong coordinating ...
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Article
Isoniazid thermal runaway simulation based on ARC data
The law of fire occurring in the reaction of self-reactive substances is unique, when heated, comparing with common solid combustibles. In this paper, the possible thermal runaway reaction of Isoniazid storage...
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Article
Horizontally growth of WS2/WO3 heterostructures on crystalline g-C3N4 nanosheets towards enhanced photo/electrochemical performance
Two-dimensional carbon-based material is attracting considerable attention in exploiting photocatalyst under visible light for photocatalytic energy conversion and storage field, e.g., photocatalytic H2 productio...
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A statistical evaluation of the liquid effluent release from NPP based on analytical methods with low detection limits
Eight liquid effluent samples from nuclear power plants (NPP) were analyzed for 63Ni, 131I, and gamma radionuclides using methods with low detection limits. The sum of the radionuclides activity concentrations of...
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Synthesis of a Valen Schiff-base bismuth(III) complex and its thermokinetic studies on the growth metabolism of S. pombe
A Valen Schiff-base ligand [1,5-bis(2-hydroxy-3-methoxybenzylidene)thiocarbonohydrazide] and its bismuth(III) complex were synthesized. The compositions and structures of two compounds were characterized by el...
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Article
RETRACTED ARTICLE: Determination of acetaminophen spatial distribution and content in tablets using confocal micro-Raman spectroscopy map**
This study focused on the development of an effective method to determine the spatial distribution and content of acetaminophen in intact tablets. We scanned tablets by confocal micro-Raman spectroscopy using ...