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877 Result(s)
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Article
Laser chemical physics I: State selective excitation
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Article
Application of laser-induced optical fiber fluorimetry to the analysis of ultralow level of uranium
A laser-induced optical fiber fluorimetry has been reported for the analysis of ultralow level of uranium. The fluorescence spectrometer includes five major components: a pulsed nitrogen laser, optical fibers,...
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Article
Kinetic studies on the solvent extraction of uranium(VI) from phosphoric acid solution with HDEHP using laser-induced optical fiber fluorimetry
Laser-induced optical fiber fluorimetry has been first used to analyze uranium(VI) concentration in the kinetic studies on the extraction of uranium(VI) between 0.5 mol/l H3PO4 solution and HDEHP-cyclohexane syst...
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Article
Soft X-ray amplification by Li-like Al10+ and Si11+ ions in recombining plasmas
Experimental studies of soft X-ray lasers were carried out on the six-beam laser facility and the LF 12 laser facility of SIOM. Using a home-made one-dimensional spatially resolved grazing incidence grating sp...
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Article
Calculation of the maximum bond order
Based on the maximum overlap method, an alternative scheme for the calculation of the maximum bond order defined by Jug is introduced to simplify the calculation procedure.
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Article
Cluster assisted formation of carbon-carbon bonds: Synthesis and crystal structures of two trinuclear heterometallic complexes CpWRu2(CO)7(μ-H)[OC(NMe2)CCHCHEt] and CpWRu2(CO)6(μ-H)[OC(NMe2)CCH(μ-η2-C6H4)]
Treatment of the carbamoyl cluster Ru3(CO)10(μ-H)(μ-η2-OC(NMe2)] with a two molar excess of CpW(CO)3C≡Cn Pr in refluxing toluene produced a heterometallic cluster complex CpWRu2(CO)7(μ-H)[OC(NMe2) CCHCHEt] (II), ...
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Article
Synthesis and magnetic properties of copper(II)-cobalt(II) complexes ofN,N′-1,2-propanedisalicylamidatocuprate(II)
The binuclear metal complexes [Cu(sampn)Co(L)2] (L=bipy, phen), have been prepared by the reaction of sodiumN,N′-1,2-propanedisalicylamidatocuprate(II) heptahydrate, Na2[Cu(sampn)] 7H2O, with a divalent metalion,...
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Article
Synthesis, spectral and magnetic studies of novel μ-oxamido heterotinuclear complexes
Three novel heterotrinuclear complexes have been prepared, [Cu2(oxdn)2Zn](ClO4)2 (1) and [Cu2(oxdn)2-M(H2O)2](ClO4)2 with M=Mn (2) and Co (3) [oxdn-oxamidobis (propionato)], and characterized by spectral data. Th...
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Article
Reactive intermediates in laser photolysis of guanosine
The photochemical reactions of aqueous solution guanosine with acetone as photosensitizer have been investigated by laser flash photolysis. From detailed kinetic analysis, the reaction mechanism has been deriv...
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Article
Chemical characterization of complexation behavior of pertechnetate with cysteine
The labeling behavior of cysteine with99TcO 4 − ion and/or99mTcO 4 − ion at different cysteine concentrati...
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Article
Synthesis, structure and magnetic studies of copper(II)-nickel(II) complexes withN,N′-bis(2-aminopropyl)oxamidocopper(II)
Three novel heterobinuclear complexes have been prepared and identified as [Cu(oxap)Ni(L)2](ClO4)2·ξH2O, where oxap denotes theN,N′-bis(2-aminopropyl)oxamido dianion and L denotes 2,2′-bipyridine (bipy), 1,10-phe...
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Article
Synthesis and magnetism of 6-nitrobenzimidazolate and imidazolate-bridged copper(II) complexes
Four new trinuclear copper(II) complexes, [Cu(phen)-(NBzIm)] (ClO4) (1), [Cu(bpy)(NBzIm)](ClO4) (2), [Cu-(Me2-bpy)(NBzIm)](Ac)·1/2H2O (3) and [Cu(Me2-bpy)-(Im)](ClO4)·1/2H2O (4) (phen = 1, 10-phenanthroline, bpy ...
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Article
Enhancement of Pt−Sn/Al2O3 catalyst stability for butane dehydrogenation by modification with Sm and Li
Stabilization methods of Pt−Sn/Al2O3 dehydrogenation catalysts by modification with Sm and Li are introduced. Pt crystallite dispersion on the support can be promoted by Sm. Li, especially when corporated with Sm...
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Article
Kinetic aspects and determination of the oxidation state of Tc in Tc-cysteine complex
The pertechnetate ion to forms a yellow complex with cysteine (λmax=420 nm) under anaerobic conditions. The kinetic order with respect to pertechnetate and cysteine has been determined by HPSEC and titration meth...
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Article
Synthesis and magnetic properties of copper(II)-lanthanoid(III)-copper(II) trinuclear complexes with N,N′-bis(2-aminoethyl)-oxamido ligand
Ten novel μ-oxamido trinuclear complexes, namely Cu2−(oxae)2Ln(ClO4)3 (Ln = Y, Pr, Sm, Eu, Gd, Tb, Dy, Ho, Er and Yb), where oxae donotes the N,N′-bis(2-aminoethyl)-oxamido dianion, were prepared and characterize...
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Article
Synthesis and magnetic properties of novel copper(II)-lanthanoid(III) heterobinuclear oxamido bridged complexes
Seven novel μ-oxamido hetero-metal binuclear complexes have been prepared and characterized, namely [Cu(oxae)-Ln(NO2-phen)2 (ClO4)](ClO4)2, where oxae denotes the N,N′-bis(2-aminoethyl)oxamido dianion, NO2-phen d...
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Article
Bonding properties and electronic structures of glycylglycinato copper(II) complexes. Molecular structure of acetylhistaminegly-cylglycinatocopper(II) dihydrate
Mixed ligand diglycinatocopper(II) complexes of the Cu(glygly)L·nH2O type, where glygly stands for [NH2-CH2 CONCH2CO2]2− and L for imidazole (n = 1.5), N-methylimidazole (n = 1), 2-methylimidazole (n = 2), 4-meth...
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Article
New method for olefin production from light alkanes
A new method is presented for olefin production by oxidative dehydrogenation-cracking of light alkanes. ZSM-5 zeolites modified by Co, Mo, K, Ca, Mg, etc., were used as catalysts. The selectivity of olefins in...
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Article
Synthesis and magnetic properties of copper(II)-MII-copper(II) trinuclear complexes with N,N′-bis(2-aminoethyl)oxamidocopper(II) [M = Co and Ni]
Two novel trinuclear complexes were prepared, namely [Cu2(oxae)2(H2O)2M] (ClO4)2, [oxae = N,N′-bis(2-aminoethyl) oxamido dianion; M = Co and Ni]. Based on elemental analyses, conductivity measurements and i.r. sp...
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Article
Synthesis and magnetic properties of new nickel(II)-copper(II)-nickel(II) trinuclear complexes with irregular spin-state structure
Four novel heterotrinuclear complexes were prepared, namely {[Ni(L)2]2[Cu(pba)]}(ClO4)2, where pba = pro-pylene-1,3-bis(oxamato) and L = 1,10-phenanthroline (phen), 5-nitro-1,10-phenanthroline (NO2-phen), 2,2′-bi...