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Chapter and Conference Paper
Crystal Engineering of Multifunctional Molecular Materials
In this paper we will focus on the crystal engineering of molecular materials exhibiting magnetic and/or electrical properties. The complexity of these materials needs of a precise design of the molecular buil...
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Chapter and Conference Paper
Hydrogen-Bonded Crystals of Exceptional Dielectric Properties
Hydrogen bonds are well known for governing the molecular association and crystal packing, as well as for their contribution to the chemical and physical properties of substances. They affect the properties of...
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Chapter and Conference Paper
Design, Characterization and Use of Crystalline Thin Film Architectures at the Air-Liquid Interface
The lecture notes describe the design, characterization and use of crystalline thin film architectures at the air-water interface. Grazing incidence X-ray diffraction (GIXD) using synchrotron radiation has bee...
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Chapter and Conference Paper
From Bonds to Packing: An Energy-Based Crystal Packing Analysis for Molecular Crystals Packing Analysis for Molecular Crystals
The analysis of the crystal structure based only on distance considerations (short-contact analysis) presents some problems, as not always the shortest contacts are the most attractive. Here, it is shown how a...
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Chapter and Conference Paper
NMR Crystallography and the Elucidation of Structure-Property Relationships in Crystalline Solids
SSNMR spectroscopy, an established technique for identifying crystalline polymorphs and solvates, can provide detailed structural information useful for rationalizing materials properties in terms of molecular...
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Chapter and Conference Paper
Signalling By Modulation of Intermolecular Interactions
The importance of intermolecular interactions in the solid-state for modulation of material properties useful for signaling is discussed. Specifically, the genesis of crystalline solvatochromism; crystalline f...
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Chapter and Conference Paper
Building Conducting Materials from Design to Devices
The electronic and structural characteristics of organic molecules that generate materials with conducting properties will be analyzed, emphasizing specially the design of the material and the methodology for ...
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Chapter and Conference Paper
Crystal Structure Determination from X-Ray Powder Diffraction Data
Many crystalline materials cannot be prepared in a suitable form for conventional single-crystal diffraction studies, and hence the successful structure characterisation and rationalisation of these materials ...
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Chapter and Conference Paper
Self-Assembled Monolayers as Templates for Inorganic Crystallization: a Bio-Inspired Approach
Nature produces a wide variety of exquisite mineralized tissues fulfilling diverse functions, and often from simple inorganic salts. Organisms exercise a level of molecular control over the physico-chemical pr...
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Chapter and Conference Paper
Case Studies on Intermolecular Interactions in Crystalline Metals
It is the purpose of this contribution to take the reader throughout a set of case studies which serve to illustrate an integrated approach which spans the design of functional π-conjugated precursors, their a...
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Chapter and Conference Paper
Complementarity: Correlating Structural Features with Physical Properties in Supramolecular Systems
In recent years a number of complementary techniques have been developed to study the correlation between crystalline structure and physical behaviour of inclusion compounds. In this article, case studies are ...
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Chapter and Conference Paper
Nanostructured Frameworks for Materials Applications
Strategies for the synthesis of frameworks materials based upon either coordination bonds or hydrogen-bonding interactions are described. The utilization of coordinate bonds for the construction of coordinatio...
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Chapter and Conference Paper
Topological Approaches to the Structure of Crystalline and Amorphous Atom Assemblies
Crystalline assemblies of atoms possess not only symmetry and periodicity but also a topology that provides additional information not explicit in a conventional description. A topological description of struc...
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Chapter and Conference Paper
Chirality In Crystals
Chirality is recognized strongly in the crystalline state and often only in the phase. Chiral supramolecular structures can be engineered by using conformationally flexible achiral or chiral compounds of axial...
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Chapter and Conference Paper
Design, Synthesis, and Characterization of Molecule-Based Magnets
The discovery of organic- and molecule-based magnets has led to several design criteria for their design and synthesis, and several families with magnetic ordering temperatures as high as ̃125°C have been repo...
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Chapter and Conference Paper
On the Calculation and Interpretation of Crystal Energy Landscapes
The energetically feasible crystal structures of a molecule can be computed for an increasing range of types of molecule, provided sufficient care is taken to ensure that their relative energies are calculated...
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Chapter and Conference Paper
Hydrogen Bonding and Concurrent Interactions
The lecture deals with the various forms of interactions with dominant electrostatic component. It points to dipole/dipole interactions as strong structure determining factor that often accompanies hydrogen bo...
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Chapter and Conference Paper
Organic Materials for Nonlinear Optics
Interest in nonlinear optics has grown continuously since these phenomena first emerged and the field now encompasses fundamental studies of the interaction of light with matter and the development of new mate...
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Chapter and Conference Paper
Biomineralization of Organic Phases Associated With Human Diseases
Crystal deposition diseases are a type of biomineralization process. Most reviews of pathological crystallization events focus on the formation of inorganic phases (e.g. calcium carbonates, calcium phosphates)...
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Chapter and Conference Paper
Surface Properties of the Binary Alloy Thin Films
The theory of order-disorder phenomena of different physical nature in binary alloy thin films of AB3 type is considered. The investigations are based on the model of the samples with restricted dimension when it...