572 Result(s)
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Chapter and Conference Paper
STRUCTURAL EVOLUTION AND POINT DEFECTS IN METAL OXIDE-BASED HIGH-κ GATE DIELECTRICS
Processing of ultra-thin high-κ metal oxide films (e.g. HfO2) for use in semiconductor devices requires exposure of these materials to potentiallyreactive solids and to both reducing and oxidizing ambients at ele...
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Chapter and Conference Paper
INTERDIFFUSION STUDIES OF HIGH-K GATE DIELECTRIC STACK CONSTITUENTS
stability of various high-κ gate dielectric materials. The role of film morphology and the resultant interdiffusion are also discussed. This paper presents a summary of recent studies of the thermal
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Chapter and Conference Paper
TRANSIENT CHARGING EFFECTS AND ITS IMPLICATIONS TO THE RELIABILITY OF HIGH-K DIELECTRICS
Unlike SiO2-based devices, various structural defects and small band gaps in high-κ gate dielectrics make high-κ devices susceptible to electron charging. In particular, fast transient charging in high-κ devices ...
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Chapter and Conference Paper
DEFECT-RELATED ISSUES IN HIGH-K DIELECTRICS
The roles of impurities and point defects are again coming to the forefront as new materials, such as high-k dielectrics, and novel device structures (e.g., double gate MOSFETs) are introduced in new generatio...
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Chapter and Conference Paper
PROBING POINT DEFECTS AND TRAPS IN STACKS OF ULTRATHIN HAFNIUM OXIDES ON (100)SI BY ELECTRON SPIN RESONANCE: INTERFACES AND N INCORPORATION
results of an electron spin resonance (ESR) analysis of (100)Si/HfO2 entities with ultrathin layers of deposited amorphous (a)-HfO2 are overviewed. The main ESR signals observed in the as-grown samples and after ...
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Chapter and Conference Paper
DEFECTS AT THE HIGH-κ /SEMICONDUCTOR INTERFACES INVESTIGATED BY SPIN DEPENDENT SPECTROSCOPIES
The interfaces between high-κ dielectrics, grown by atomic layer deposition, and semiconductors have been characterized using various electrically detected magnetic resonance spectroscopy techniques. The domin...
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Chapter and Conference Paper
ELECTRICALLY ACTIVE INTERFACE AND BULK SEMICONDUCTOR DEFECTS IN HIGH-K / GERMANIUM STRUCTURES
Metal insulator semiconductor field effect transistors (MOSFETs) with high-k dielectric gates fabricated on high mobility semiconductors such as germanium could be used for future high performance logic device...
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Chapter and Conference Paper
ELECTRICAL DEFECTS IN ATOMIC LAYER DEPOSITED HFO2 FILMS ON SILICON: INFLUENCE OF PRECURSOR CHEMISTRIES AND SUBSTRATE TREATMENT
Capacitance-voltage, deep level transient spectroscopy, and conductance transient measurement results on atomic layer deposited (ALD) Al/HfO2/Si structures are presented here. These methods assist in establishing...
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Chapter and Conference Paper
CAN LEIS SPECTRA CONTAIN INFORMATION ON SURFACE ELECTRONIC STRUCTURE OF HIGH-K DIELECTRICS?
While investigating the surface composition of thin layers containing Hf with low energy ion spectroscopy (LEIS) utilizing He+ ions with energy E0=300÷800 eV, the fine structure of Hf line was observed. Hf spectr...
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Chapter and Conference Paper
MONITORING OF FERMI LEVEL VARIATIONS AT METAL/HIGH-K INTERFACES WITH IN SITU X-RAY PHOTOELECTRON SPECTROSCOPY
A method to monitor Fermi level changes at the metal/high-k interface depending on the materials of choice and peculiarities of interface formation is presented. The method is based on the deposition of ultrat...
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Chapter and Conference Paper
DIELECTRIC AND INFRARED PROPERTIES OF ULTRATHIN SiO2 LAYERS ON Si(100)
The occurrence of an ultrathin SiO2 oxide layer at the interface between silicon and high-k dielectrics in metal-oxide-semiconductor devices contributes to degrading the capacitance of the gate stack. In this wor...
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Chapter and Conference Paper
EXTREMELY HIGH-DENSITY CAPACITORS WITH ALD HIGH-K DIELECTRIC LAYERS
This paper describes the deposition of high-k dielectric layers, Al2O3, Ta2O5, HfO2, etc, in high aspect ratio pores aiming for a higher capacitance density at a given breakdown voltage. The most emerging technol...
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Chapter and Conference Paper
INTERFACE FORMATION DURING EPITAXIAL GROWTH OF BINARY METAL OXIDES ON SILICON
The Si/dielectric interface properties influence the device performance significantly. Often the interface is not stable and changes during and after the growth. For a better understanding of the interface and...
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Chapter and Conference Paper
CORRELATION BETWEEN DEFECTS, LEAKAGE CURRENTS AND CONDUCTION MECHANISMS IN THIN HIGH-K DIELECTRIC LAYERS
Results on leakage currents and conduction mechanisms in various high-k dielectric layers (Zr-, Hf-, HfTi-silicates and Ta2O5) are presented. It is demonstrated that small alteration of the dielectric composition...
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Chapter and Conference Paper
ON THE CHARACTERIZATION OF ELECTRONICALLY ACTIVE DEFECTS IN HIGH-к GATE DIELECTRICS
A number of techniques are discussed with regard the measurement of electronically active defects in high-к gate dielectrics. Following a short review of 1st-order trap** kinetics, a discussion of its limita...
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Chapter and Conference Paper
HIGH-K GATE STACKS ELECTRICAL CHARACTERIZATION AT THE NANOSCALE USING CONDUCTIVE-AFM
A purposely developed Conductive Atomic Force Microscope with enhanced electrical performance (ECAFM) has been used for the electrical characterization of HfO2/SiO2 gate stacks. The conduction of the fresh (wi...
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Chapter and Conference Paper
CHARACTERIZATION AND MODELING OF DEFECTS IN HIGH-K MEASUREMENTS LAYERS THROUGH FAST ELECTRICAL TRANSIENT
An original dynamic analysis technique allows the characterization of VT shift transients for full time range. Extensive data set versus voltage, time, temperature and operating mode is shown to fit with direct t...
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Chapter and Conference Paper
ON THE IMPORTANCE OF ATOMIC PACKING IN DETERMINING DIELECTRIC PERMITTIVITIES
The role of the network structure in determining the dielectric constant of binary and ternary oxide insulators is outlined. Seemingly anomalous behavior observed in rare-earth sesquioxides, Ta2O5-TiO2 mixed oxid...
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Chapter and Conference Paper
IMPACT OF HIGH-κ PROPERTIES ON MOSFET ELECTRICAL CHARACTERISTICS
The integration of high-κ dielectrics in MOSFET devices is beset by many problems. In this paper a review on the impact of defects in high-κ materials on the MOSFET electrical characteristics is presented. Bes...
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Chapter and Conference Paper
DISORDERED STRUCTURE AND DENSITY OF GAP STATES IN HIGH-PERMITTIVITY THIN SOLID FILMS
Metal-oxide-semiconductor structures based on high-permittivity dielectric thin films of HfO2, ZrO2, Al2O3, TiO2, Ta2O5, and Nb2O5, were subjected to capacitance-voltage and conductance transient measurements as ...