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Open AccessVanadium Phosphorus Oxide/Siliceous Mesostructured Cellular Foams: efficient and selective for sustainable acrylic acid production via condensation route
A new type of supported vanadium phosphorus oxide (VPO) with self-phase regulation was simply fabricated (organic solvent free) for the first time by depositing the specific VPO precursor NH4(VO2)HPO4 onto the Si...
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Article
Surface Cobalt Silicate and CoO x Cluster Anchored to SBA-15: Highly Efficient for Cyclohexane Partial Oxidation
The present investigation showed that the surface cobalt silicate and CoO x cluster anchored to SBA-15 are highly efficient heterogeneous catalysts for the cyclohexane part...
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Article
Cyclohexane Oxidation Over Size-Uniform Au Nanoparticles (SBA-15 hosted) in a Continuously Stirred Tank Reactor Under Mild Conditions
Cyclohexane oxidation was operated in a continuously stirred tank reactor at system pressures of 0.6–1.0 MPa under an air-like O2/N2 atmosphere (rather than pure O2). Catalytic performance was investigated over A...
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Article
A Comparison Study on the Structure and Performance of Mo–V–O and Mo–V–Te–O Catalysts Synthesized Hydrothermally with Ultrasonic Pretreatment for Propane Oxidation
The Mo1.00V0.80O n and Mo1.00VαTe0.17O n (α = 0.40–1.00) catalysts were prepared hydrothermally with ultrasonic pretreatment for propane parti...
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Article
Activation and conversion of propane over nano-sized MnOx-Moy(M=Cu, V) promoted sulfated yttria-stabilized zirconia-titania catalysts
Nanosized MnOx-MOy(M=Cu, V)-promoted sulfated yttria-stabilized zirconia-titania catalysts were synthesized and studied for propane activation and conversion. The derived catalysts are amorphous in general and th...
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Article
Influence of the way of preparing vanadium phosphorus oxide (VPO) precursor and introducing multi-additives on the reaction performance
The VPO system synthesized in aqueous medium and doped with Mo, Zr and Znshowed high maleic anhydride (MA) selectivity at fair butane conversion. Thecatalytic performance was found to depend not only on the so...
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Article
A Study on VPO Specimen Supported on Aluminum-Containing MCM-41 for Partial Oxidation of n-Butane to MA
Dispersed vanadium–phosphorus oxide species supported on Al-MCM-41 with different vanadium loadings have been synthesized for the first time for partial oxidation of butane to MA. It was found that the VPO spe...
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Article
The structure and surface acidity of zirconia-supported tungsten oxides
The structure and surface acidity of zirconia-supported tungsten oxide are studied by using BET, XRD, FT Raman, Tian–Calvet microcalorimetry as well as XPS. Three different crystal forms of ZrO2 and their hydroxi...