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Article
Thermal decomposition of peroxide derivatives of polyfluorinatedβ-ketoesters
The thermal flow microcalorimetric method was used to determine the kinetic parameters for the thermal decomposition of peroxide derivatives of polyfluorinatedβ-ketoesters and the decomposition products were esta...
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Article
Synthesis of Perfluorinated Dioxo Esters from Dimethyl Perfluoroadipate
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Article
Specific features of amidoalkylation of 6-hydroxy-5-isopropyl-2-thioxo-2,3-dihydropyrimidin-4(1H)-one
During the synthesis of new structural analogs of isothiobarbamine, the amidoalkylation of 6-hydroxy-5-isopropyl-2-thioxo-2,3-dihydropyrimidin-4(1H)-one was found to give a mixture of mono-, di-, and trisubstitut...
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Article
Regiospecific S-aminoalkylation of 5-substituted 6-hydroxy-2-thiouracil derivatives in the synthesis of structural analogs of isothiobarbamine
Regiospecific S-monoaminoalkylation of 5-substituted derivatives of 6-hydroxy-2-thiouracil with free N,N-dialkyl-N-(2-chloroethyl)amines in anhydrous PriOH was described for the first time. In compliance with the...
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Article
Synthesis and biological properties of novel structural analogs of isothiobarbamine
Novel structural analogs of isothiobarbamine, which differ from the prototype scaffold by the substituent at position 2 of the pyrimidine heterocycle, were for the first time synthesized and characterized. Dat...