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Electron capture in spin-trap capped peptides. An experimental example of ergodic dissociation in peptide cation-radicals
Electron capture dissociation was studied with tetradecapeptides and pentadecapeptides that were capped at N-termini with a 2-(4′-carboxypyrid-2′-yl)-4-carboxamide group (pepy), e. g., pepy-AEQLLQEEQLLQEL-NH2, pe...