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Article
Dehydrocyclodimerization of n-Butane into Aromatic Hydrocarbons in the Gas-Phase and under Supercritical Conditions on a ZSM-5 Zeolite in the H-Form and Modified with Ga or Pt
A comparative study of n-butane conversion into aromatic hydrocarbons on a ZSM-5 zeolite in the H-form and modified with gallium or platinum at 530°C in the gas phase (at 1 atm) or under supercritical conditions ...
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Article
Self-Condensation of Acetone of Strontium Stannate under Supercritical Conditions
Aldol condensation of acetone on strontium stannate is studied at a temperature of 250–400°C and a pressure of 2.5 and 12.5 MPa. The main reaction products are mesityl oxide and isophorone. It is shown that th...
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Article
Structure and Catalytic Properties of Magnesium Stannate in the Acetone Condensation Reaction
The MgSnO3-450 and MgSnO3-750 catalysts of different morphologies, synthesized by calcining magnesium hydroxystannate MgSn(OH)6 at 450 and 750°C, respectively, are studied in the aldol condensation of acetone und...
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Article
Utilization of Acetone, By-Product of Cumene Process for Phenol Production, via BaSnO3-Catalyzed Aldol Condensation
The aldol condensation of acetone under supercritical conditions at 300–400°C and 11.0 MPa was carried out on BaSnO3-450 and BaSnO3-750 catalysts prepared by calcination of BaSn(OH)6 at 450 and 750°C, respectivel...
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Article
Tandem Reactions in Acetone–Isopropanol System on MgSnO3 Catalyst under Supercritical Conditions
The results of a study of tandem reactions - aldol-crotonic condensation and hydrogenation by the mechanism of hydride transfer in acetone-isopropanol mixtures on a МgSnО3 catalyst at 300–400°C and 12.0 MРa are p...