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4,802 Result(s)
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Article
Studies in the field of depsipeptides LI. Mass-spectrometric study of cyclotetradepsipeptides of regular structure
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The mass-spectrometric behavior of various cyclotetradepsipeptides of regular structure has shown that the CO
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The glycosides ofEleutherococcus senticoccus Max. I. Isolation and some properties of eleutherosides B and E
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From the roots of prickly eleutherococcus (Eleutherococcus senticoccus Max.) we have isolated a physiological...
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The glycosides ofApocynum androsaemifolium L. II. The structure of apobioside
The roots of the plantApocynum androsaemifolium L. contain a new steroid diglycoside, apobioside, which has the structure cannogenin-(3)-β-D-cymaropyranoside-(4)-β-D-glucopyranoside.
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Article
Reduction of some D-homosteroids with an aromatic a ring by alkali metals under the conditions of the birch reaction. I
In the Birch reduction of steroid compounds with a phenylbutadiene grou**, i.e., the ketal of 3-methoxy-Δ1, 3, 5(10), 8, 14-D-homoestrapentaen-17a-one (III), the corresponding ketone (IIIa), and 3-methoxy-Δ1, 3...
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Article
The structure of the alkaloid renardine. III. Structure of dihydrodesoxyotonecine
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N-methyl-N-(β-carboxyethyl)-γ-amino-α-methylbutyric acid is a product of oxidative degradation of dihydrodeso...
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The flavonoids of the cruciferae I; robinin and zhealin from the fruit ofCheiranthus allionii
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The triglycoside robinin and a new diglycoside, zhealin, have been isolated from the fruit ofCheiranthus alli...
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Glycosides from ginseng roots IV. Isolation of new glycosides from ginseng
1. New glycosides — panaxosides C, D, E, and F — have been isolated from the root of ginseng by partition chromatography.
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Article
The saponin ofAcanthophyllum gypsophiloides
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Article
Reduction of some D-homosteroids with an aromatic a ring with alkali metals under the conditions of Birch's reaction. II.
1. The reduction of 3-methoxy-D-homoestra-1, 3, 5(10), 8-tetraen-17aβ-ol (IV) with alkali metals in the presence of ammonium chloride or alcohol gives, in addition to 8β, 9α-dihydro derivatives, the 8α, 9α and...
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Article
Elucidation of the composition of pastinacin and isolation of sphondin
A preparation of pastinacin has been separated by preparative chromatography on acidic alumina into three isomeric monomethylfurocoumarin components, bergaptene, sphondin, and xanthotoxin. Their ratio in the p...
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Article
Synthesis and study of the properties of 6-O-(α-L-aspartyl)-D-glucose
1. The carbodiimide method has been used for the first time for the synthesis of aminoacyl derivatives of glucose with aspartic acid.
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Article
Substrate specificity of microbiological conversions of steroids by means ofActinomyces albus ATCC 3006
In a comparison of the substrate specificity of the action of a culture ofActinomyces albus 3006 and a cell-free preparation obtained from the mycelium ofA. albus 3006, it was found that the spectrum of the actio...
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Article
Variants of the complete synthesis of d,l-19-nortestosterone, d,l-19-norandrost-4-ene-3, 17-dione, and their stereoisomers
The complete synthesis of d,l-19-nortestosterone (I) and its 8-iso- and 9, 10-iso- stereoisomers, and also the synthesis of d,l-19-norandrosten-4-ene-3, 17-dione (VI) and its 9, 10-iso-stereoisomer (IX), has been...
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Article
Diterpene hydrocarbons of the resin ofPinus sibirica R. Mayr.
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Glycosides from ginseng roots. VI. Structure of the carbohydrate chain of panaxoside A
The structure of the carbohydrate part of panaxoside A has been established by methylation with subsequent hydrolysis and identification of the methylated monosaccharides.
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Article
Cardenolides of the pods ofOrnithogalum magnum Krasch. et Schischk
Steroid glycosides of the cardenolide group have been found inOrnithogalum magnum.
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Article
Variants of the complete synthesis of d,l-estrone from 1-vinyl-6-methoxytetralol and 2-methylcyclopentane-1,3-dione
Various routes for the synthesis of the methyl ether of d,l-estrone (XI) and of d,l-estrone itself (XIII) have been investigated. The best results were obtained by synthesis according to the route IV → V → VI → I...
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Article
The fatty acid composition of the phospholipids of cottonseed oil
1. The phospholipids of cottonseed oil contain ten fatty acids.
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Investigation of the alkaloids ofVinca major,V. pubescens, andV. rosea. The structure of majdine [1]
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Cardenolides ofSecurigera securidaca. II.
The seeds ofSecurigera securidaca have been found to contain a cardiac glycoside securidaside, which is securigenin xyloglucoside. By stepwise enzymatic hydrolysis, securidaside can be decomposed into the monoxyl...