3 Result(s)
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Article
Immobilized phosphine–phosphite rhodium complexes: highly active and enantioselective catalysts for asymmetric hydrogenation under continuous flow conditions
The asymmetric hydrogenation of benchmark substrates dimethyl itaconate and (Z)-α-acetamidocinnamic acid methyl ester with chiral pentane-2,4-diyl-based phosphine–phosphite Rh complexes immobilized on the support...
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Article
Aminoalkyl-phosphine (P,N) ligands with pentane-2,4-diyl backbone in asymmetric allylic substitution reactions
The asymmetric allylic substitution reaction of rac-1,3-diaryl-2-propenyl acetates with several C- and N-nucleophiles catalyzed by the palladium-complexes of eleven structurally analogous aminoalkyl-phosphines (P...
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Article
A Continuous-Flow System for Asymmetric Hydrogenation Using Supported Chiral Catalysts
Highly active immobilized hydrogenation catalytic systems were used in the H-Cube™ hydrogenation reactor. “In situ” produced [Rh(COD)((S)-MonoPhos)2]BF4 complex was immobilized on commercially available Al2O3 and...
