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The Virtue of Michael-Type Addition Processes in the Design of Transition Metal-Promoted Cyclizative Cascade Reactions
Cascade reactions involving a transition metal-promoted step and a Michael-type addition process have emerged as a powerful tool to construct...
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Domino Heck-Pericyclic Reactions
Palladium-catalyzed cross-coupling reactions and cycloadditions as well as electrocyclic transformations can efficiently be combined in one-pot...
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Medicinal Properties of Organometallic Compounds
Although organometallic compounds are ubiquitous in nature, synthetic organometallic compounds are generally considered to be toxic or...
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Cascade and Sequential Catalytic Transformations Initiated by Ruthenium Catalysts
Ruthenium holds a prominent position among the efficient transition metals involved in catalytic processes. Molecular ruthenium catalysts are able...
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Cascade Reactions Involving Pauson–Khand and Related Processes
The Pauson–Khand [2 + 2 + 1] cycloaddition is one of the best ways to construct a cyclopentenone. It implies the formation of three new bonds and...
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Gait Planning for Soccer-Playing Humanoid Robots
Gait planning for humanoid walking and penalty kicking, the two fundamental tasks for the current humanoid soccer competition, is addressed in this...
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Nd:YAG – Laser – GMA – Hybrid Welding in Shipbuilding and Steel Construction
The paper deals with the Nd:YAG-laser – GMA – hybrid welding process for the use in shipbuilding and steel construction. The advantages of a laser –...
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Computer Vision Sensing and Intelligent Control of Welding Pool Dynamics
This paper presents a successful application of intelligent technologies, such as computer vision, image processing fuzzy-neural networks, for...
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Surface Shape Reconstruction of Weld Pool during Pulsed GTAW from Its Single Image
This paper addresses an improved algorithm of shape from shading with a single real image, and its application on three-dimensional surface...
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Adaptive Neuro-Fuzzy Control of Systems with Unknown Time Delay
We present an adaptive fuzzy logic controller, which learns a lower-order model of the system via an on-line Neural Network (NN) identification...
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On Singular Perturbation Based Inverse Dynamics Control for a Two-Link Flexible Manipulator
Based on singular perturbation technology, the flexible-link manipulator system model was divided into two sub-systems, one for slow sub-system...
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Map Building and Localization for Autonomous Mobile Robots
In this chapter, we present our recent works on map building and localization algorithms for autonomous mobile robots. We start with the...
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Estimation of Oxygen Concentration Using Dynamic Recurrent Neural Network Based on PCA
At present, much more research in the field of soft-sensing modeling is concerned. In the method of building soft-sensing models, artificial neural...
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Generation of Alkene Radical Cations by Heterolysis of β-Substituted Radicals: Mechanism, Stereochemistry, and Applications in Synthesis
The experimental basis for the formation of alkene radical cations by the heterolysis of alkyl radicals bearing leaving groups at the β position...
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Unusual Radical Cyclisations
Methods for solving the problems associated with reverse ring opening of small-ring intermediates are described. For three- and four-membered rings...
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Palladium-Catalyzed Cycloaddition Reactions of Arynes
The transition-metal-catalyzed cyclotrimerization of alkynes has been used extensively in synthesis during the past 25 years. However, until recently...
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Co-Oligomerization of 1,3-Butadiene and Ethylene Promoted by Zerovalent ‘Bare’ Nickel Complexes
The transition-metal-catalyzed cyclooligomerization of 1,3-dienes and the co-oligomerization of 1,3-dienes and alkenes, that involve the...
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Organolithium in Asymmetric Processes
The development of asymmetric processes has been the focus of industrial research as most of the molecules of pharmaceutical interest contain chiral...
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Rhodium/Ruthenium Applications
Asymmetric catalytic hydrogenation and hydrogen transfer reactions of various substrates such as prochiral ketones and olefins using Rh(I) and Ru(II)...
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Organometallic and Metallo-Organic Precursors for Nanoparticles
Several synthetic methods for the preparation of semiconductor nanoparticles have been reported. Colloidal and organometallic routes have probably...