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Activation of Inert C–H Bonds
The development of catalytic reactions involving carbon–hydrogen bond cleavage is one of the most attractive research subjects in organic and...
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Ruthenium-Catalyzed C–C Bond Formation
Molecular ruthenium catalysts are now currently used to perform selective carbon–carbon bond formation by combination of simple substrates. Their...
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Ruthenium Vinylidenes and Allenylidenes in Catalysis
During the last decade, ruthenium catalysis, including asymmetric catalysis, has attracted increasing interest owing to its wide range of...
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Ruthenium-Promoted Radical Processes Toward Fine Chemistry
Ruthenium holds a prominent position among the many transition metals used in radical chemistry. The dichlorotris(triphenylphosphine) complex...
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Cyclopropanation with Ruthenium Catalysts
In this decade, a variety of ruthenium complexes have been intensively investigated that exhibit catalytic activity for cyclopropanation of olefins...
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Metal Carbene Reactions from Dirhodium(II) Catalysts
The dirhodium(II) core is a template onto which both achiral and chiral ligands are placed so that four exist in a paddle wheel fashion around the...
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Chromium-Templated Benzannulation Reactions
Since its discovery the chromium-mediated benzannulation reaction has been developed into a unique and useful tool in organic synthesis. In this...
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Photoinduced Reactions of Metal Carbenes in Organic Synthesis
The photoinduced reactions of metal carbene complexes, particularly Group 6 Fischer carbenes, are comprehensively presented in this chapter with a...
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Gels as Templates for Nanotubes
The design of artificial models for “biomineralization” processes that utilize sol-gel polycondensation has led to a merging of inorganic materials...
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Beads Arraying and Beads Used in DNA Chips
The present article draws a general picture of the bead assisted DNA immobilization on chips. The authors wish to present these systems since...
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New P-Chirogenic Phosphine Ligands and Their Use in Catalytic Asymmetric Reactions
This chapter is concerned with an update on the preparation and applications of optically active phosphine ligands which bear the chiral center at a...
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Donor-Acceptor Complexes of Low-Coordinated Cationic π-Bonded Phosphorus Systems
Cationic low-coordinated π-bonded phosphorus compounds add Lewis donors, such as amines or phosphines. In contrast to the trigonal bipyramide formed...
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Electrochemical Adsorption Technique for Immobilization of Single-Stranded Oligonucleotides onto Carbon Screen-Printed Electrodes
The data reported in literature demonstrate that screen-printed carbon electrodes are very suitable for supporting nucleic-acid layers and to...
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Chiral Diaminocarbene Complexes, Synthesis and Application in Asymmetric Catalysis
The synthetic routes to optically pure N-heterocyclic carbene (NHC) complexes and their application in asymmetric catalysis is reviewed. Chiral...
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Non-covalent Immobilization of Catalysts Based on Chiral Diazaligands
The immobilization of chiral catalysts through non-covalent methods, as opposed to covalent immobilization, allows an easier preparation of chiral...
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State of the Art. Chemical Synthesis of Biophosphates and their Analogues via PIII Derivatives
This chapter is concerned with preparation and applications of tricoordinate phosphorus compounds in synthesis of biophosphates and their structural...
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Hybrid Organic-Inorganic Materials Based on Organophosphorus Derivatives
Because P-O-Metal and P-C linkages are quite stable, organophosphorus derivatives offer a general alternative to silicon-based coupling in the field...
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Electrochemistry and Electrogenerated Chemiluminescence of Semiconductor Nanocrystals in Solutions and in Films
A retrospective overview of electrochemical studies of semiconductor nanocrystals (NCs) is given. The electrochemical behavior of monodisperse NCs...
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Electronic Structure and Energetics of Fullerites, Fullerides, and Fullerene Polymers
Cohesive mechanisms and electronic properties of C60 fullerites, various C60 compounds including superconducting alkali fullerides and alkaline-earth...
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Ligand-Driven Light-Induced Spin Change (LD-LISC): A Promising Photomagnetic Effect
“Ligand-driven light-induced spin change” (LD-LISC) is a photomagnetic effect based on the modulation of the ligand-field strength of a suitable...