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  1. No Access

    Article

    Direct electrochemical synthesis of complex fluorides of groups IV and VI elements

    A method was developed for the direct synthesis of the complex hexafluorides of Ti, Zr, and Hf, and also the trifluorides of divalent Mo and W, by the anodic solution of the metals in the presence of fluoride ...

    V. A. Shreider, I. N. Rozhkov in Bulletin of the Academy of Sciences of the… (1979)

  2. No Access

    Article

    Adsorption on the electrode as a factor in determining the character of the anodic fluorination of organic compounds

    1. The electrolysis of pivalic acid in the presence of tetraethylammonium fluoride hydrofluoride on Pt leads to ...

    I. N. Rozhkov, V. A. Shreider in Bulletin of the Academy of Sciences of the… (1977)

  3. No Access

    Article

    Sorption of intermediate radicals as a factor determining the kinetics of the kolbe synthesis

    V. A. Shreider, I. N. Rozhkov… in Bulletin of the Academy of Sciences of the… (1977)

  4. No Access

    Article

    Reactivity of tetraalkyl ammonium fluorides in aprotic solvents

    1. The fluorine dihydrate anion in an aprotic medium is an ambidentate ion and can serve as a source of both the...

    I. N. Rozhkov, N. D. Kuleshova in Bulletin of the Academy of Sciences of the… (1976)

  5. No Access

    Article

    Anodic oxidation of olefins in presence of fluorine anion

    1. The anodic oxidation of olefins in the presence of fluorine anion can be accompanied by the addition of two f...

    I. N. Rozhkov, I. Ya. Aliev, I. L. Knunyants in Bulletin of the Academy of Sciences of the… (1976)

  6. No Access

    Article

    Anodic synthesis of 2,4,6-tri-tert-butyl-p-quinone fluoride

    I. Ya. Aliev, I. N. Rozhkov, I. L. Knunyants in Bulletin of the Academy of Sciences of the… (1974)

  7. No Access

    Article

    Synthesis of difluorocyclohexadienone by the anodic oxidation of p-fluorophenol derivatives

    I. Ya. Aliev, I. N. Rozhkov, I. L. Knunyants in Bulletin of the Academy of Sciences of the… (1973)

  8. No Access

    Article

    Generation of carbanions of weak ch acids under the influence of fluoride anion

    1. A study was made of the reaction of fluoride ion with weak CH acids.

    I. N. Rozhkov, N. D. Kuleshova… in Bulletin of the Academy of Sciences of the… (1973)

  9. No Access

    Article

    Synthesis of trityl fluoride by anodic oxidation of triphenylmethane in the presence of fluorine anion

    I. N. Rozhkov, I. L. Knunyants in Bulletin of the Academy of Sciences of the… (1972)

  10. No Access

    Article

    Anodic fluorination of benzene

    1. A study was made of the possibility of fluorination at high values of the anode potential.

      ...

    I. N. Rozhkov, A. V. Bukhtiarov… in Bulletin of the Academy of Sciences of the… (1972)

  11. No Access

    Article

    Reaction of ethanesulfenyl chloride with N,N-diethylethanesulfenamide

    The reaction of N,N-diethylethanesulfenamide with ethanesulfenyl chloride or with diethylamine hydrochloride leads to the formation of N,N-diethyl-β,β-bis(ethylthio)vinylamine, diethyl disulfide, anddiethyl trisu...

    I. L. Knunyants, I. N. Rozhkov… in Bulletin of the Academy of Sciences of the… (1971)

  12. No Access

    Article

    Electrochemical fluorination at high anodic potentials

    I. L. Knunyants, I. N. Rozhkov… in Bulletin of the Academy of Sciences of the… (1971)

  13. No Access

    Article

    Behavior of sulfenamides in anhydrous hydrogen fluoride

    1. The action of anhydrous HF on sulfenamides was studied. HF cleaves the S-N bond in the sulfenamide molecule w...

    I. L. Knunyants, I. N. Rozhkov in Bulletin of the Academy of Sciences of the… (1970)

  14. No Access

    Article

    Electrochemical fluorination of aliphatic nitro compounds

    1. The electrochemical fluorination of aliphatic nitro compounds in anhydrous hydrogen fluoride was investigated...

    A. V. Bukhtiarov, I. N. Rozhkov… in Bulletin of the Academy of Sciences of the… (1970)

  15. No Access

    Article

    A new method of introducing fluorine into the aromatic ring

    I. L. Knunyants, I. N. Rozhkov… in Bulletin of the Academy of Sciences of the… (1970)

  16. No Access

    Article

    Electrochemical fluorination in anhydrous organic solvents

    1. The electrolysis of solutions of inorganic fluorides in anhydrous organic solvents was investigated. Electroc...

    A. V. Bukhtiarov, I. N. Rozhkov… in Bulletin of the Academy of Sciences of the… (1970)

  17. No Access

    Article

    Reduction of sulfenyl chlorides by amines

    1. The reduction of sulfenyl chlorides by amines has been investigated.

    N. T. Ioffe, M. I. Kalinkin, I. N. Rozhkov… in Bulletin of the Academy of Sciences of the… (1969)

  18. No Access

    Article

    Electrochemical fluorination of sulfones

    Perflurodiethylsulfone and perfluoroethanesulfonyl fluoride are obtained during electrochemical fluorination of diethylsulfone. In the case of tetramethylenesulfone one C — S bond is broken and perfluorobutane...

    I. N. Rozhkov, A. V. Bukhtiarov… in Bulletin of the Academy of Sciences of the… (1969)

  19. No Access

    Article

    Aliphatic fluoro nitro compounds Communication 6. Some reactions of polyfluoronitroalkanes

    1. In the halogenation of the sodium salt of 1,1,1-trifluoro-2,2-dihalo-2-nitroethanes are formed exclusively.

      ...

    I. L. Knunyants, L. S. German, I. N. Rozhkov in Bulletin of the Academy of Sciences of the… (1966)

  20. No Access

    Article

    Aliphatic fluoro nitro compounds Communication 5. Proton magnetic resonance spectra and ionization constants of polyfluoronitroalkanes

    1. The PMR spectra of a number of nitro compounds were studied. As in the case of other electronegative groups, ...

    I. L. Knunyants, L. S. German, I. N. Rozhkov in Bulletin of the Academy of Sciences of the… (1966)

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