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Chapter
Magnetization, Flux Creep and Transport in Tl-Ca-Ba-Cu-O Thin Films
The enormous experimental and theoretical effort on high-temperature copper-oxide-based superconductors began with the La-Ba-Cu-O system [1], shifted to the Y-Ba-Cu-O system [2], and recently has focused on th...
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Chapter
Preparation of Thin and Thick Film Superconductors in the Tl-Ca-Ba-Cu-O System
The advent of high temperature superconductivity in Cu-O based materials has catalyzed a tremendous amount of activity in the synthesis, characterization and application of these materials [1]. The recent disc...
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Article
Chemical Preparation of Powders and Films for High Temperature Superconductors
A precipitation process has been developed to prepare precursor powders which can be calcined and sintered to form high critical temperature superconductors such as YBa2Cu3O7−x. Precursor powders are prepared usi...
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Article
Synthesis and Properties of YBaSrCu3O6.9 Prepared from Soluble Precursors
Solution chemistry routes have been used to prepare single-phased superconducting ceramics of YBaSrCu3O6.9 (1113). Resistivity measurements on air annealed samples showed a superconducting onset temperature of 85...
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Article
Improved Magnetization for YBa2Cu3O7-δ Annealed in Oxygen Above 1000°C
Air sintering and subsequent oxygen annealing at high temperatures are integral to the production of ceramic superconducting YBa2Cu3O7-δ. We present results directed toward optimizing the temperature for these tw...
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Article
Origin of Paramagnetic Defect in Single Crystal and Ceramic B4C
We compare electron spin resonance (ESR) spectra of B4C samples made by three methods. The samples are 1) two ceramics made by hot-pressing boron and carbon powders, 2) a polycrystal made by carbothermic reductio...
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Article
Bulk Ceramic and Screen Printed EuBa2Cu3O7-δ
The structural, magnetic and electrical properties of EuBa2Cu3O7-δ have been investigated both for bulk ceramics and screen printed thick films. The bulk ceramic reaches zero resistance at 92 K, and has large int...
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Article
Freestanding Films of YBa2cu3O6.9
Thick (20–300 /im) freestanding films of ceramic YBa2Cu3O0–9 have been obtained by resintering YBa2Cu3O0–9 powder in air after screen printing onto fused silica substrates. An interfacial reaction occurs between ...
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Article
Bulk Superconductivity in La2CuO4
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Article
Reoxygenation of vacuum-annealed YBa2Cu3O6.9
Vacuum-annealed samples of single-phase orthorhombic YBa2Cu3O6.9 have been reoxygenated. The vacuum-annealed material is tetragonal, semiconducting at room temperature, and shows no superconductivity. Upon anneal...
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Article
Variation of the pressure dependence of the superconducting transition temperature with x in La1−xSrx CuO4
Hydrostatic pressure measurements of the superconducting transition temperature were made as a function of x in La2−xSrx CuO4. A sharp change in the behavior occurs between x = 0.2 and 0.25 in that the pressure d...
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Chapter
Grain Decoupling at Low Magnetic Fields in Ceramic YBa2Cu3O7-δ
The ongoing series of discoveries of new materials with ever higher transition temperatures has generated an unprecedented flood of research activity in recent months, particularly on the 90 K superconductors ...
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Chapter
X-Ray Diffraction Studies of Shock-Synthesized Zinc Ferrite
Mechanically-blended stoichiometric powder mixtures of zinc oxide and ferric oxide have been subjected to high pressure shock wave loading between 7.5 and 27 GPa. By varying the initial packing densities betwe...
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Chapter
Mossbauer Study of Shock-Synthesized Zinc Ferrite
Mössbauer spectroscopy has been used to characterize ZnO-Fe2O3 powder mixtures subjected to shock loading at 22 GPa with associated peak shock temperatures ranging from 300°C to 655°C. The 57Fe spectra for the sh...
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Chapter
Deuteron Magnetic Resonance in a-Zr2PdD2.9
Deuteron Magnetic Resonance (DMR) measurements at 30.7 MHz have been performed on an a-Zr2PdD2.9 sample between 19 and 460 K. A Bruker CXP 200 spectrometer and a cryogenic probe were used to examine Fourier trans...
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Chapter
Magnetic Properties of Shock-Synthesized and Furnace-Reacted Zinc Ferrite
The static magnetic properties of spinel structure zinc ferrite are compared for products from shock synthesis and conventional isothermal reaction using a stoichiometric mixture of zinc oxide and ferric oxide...
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Chapter
Subthreshold Generation of Free Radicals in Shock-Loaded Organic Solids
A wide variety of chemical reactions have been observed in organic compounds subjected to shock loading [1]. A shock wave in condensed media produces a unique and violent environment which is characterized by ...
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Chapter
Chemical Synthesis under High Pressure Shock Loading
Many reports of chemical synthesis under high pressure shock loading have been published over the past thirty years, but little progress has been made in develo** an understanding of the mechanisms responsib...
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Chapter
Shock-Induced Modification of Inorganic Powders
Early exploratory work in Japan,1, 2 the Soviet Union3, 4 and the United States5, 6 demonstrated that high pressure shock-wave loading such as produced by the detonation of high explosives or high speed projectil...
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Chapter
Densification Kinetics of Shock-Activated Nitrides
In 1966, Bergmann and Barrington1 reported that, for a variety of oxide and carbide powders, improvement in the sintering behavior was obtained when the powders were subjected to explosive shock treatment. They c...