Definition
The Platinum Group Elements (PGE: Osmium, Iridium, Ruthenium, Rhodium, Platinum, and Palladium), also known as platinum group metals and platinoids, are transition metals located in the d-block of the Periodic Table of Elements (Groups VIII, IX, and X, Periods 5 and 6). The atomic radii of the Os, Ir, and Pt subgroup, caused by the lanthanide contraction of the 4f group elements, are similar to those of the Ru, Rh, Pd subgroup of the PGE. The almost doubling of the number of nucleons with the same atomic radii makes Os, Ir, and Pt the densest elements on Earth. Based on their behavior in magmatic systems, the PGE are subdivided into the iridium-group PGE (Ir-PGE: Os, Ir, Ru, Rh) and the palladium-group PGE (Pd-PGE: Pt, Pd) (Barnes et al. 1985; Barnes 1999).
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References
Alard O, Griffin WL, Lorand J-P, Jackson SE, O’Reilly SY (2000) Non-chondritic distribution of the highly siderophile elements in mantle sulfides. Nature 407(6806):891–894
Arculus RJ, Delano JW (1981) Siderophile element abundances in the upper mantle – evidence for a sulfide signature and equilibrium with the core. Geochim Cosmochim Acta 45(8):1331–1343
Barnes S-J (1999) Elements: platinum group. In: Marshall CP, Fairbringe RW (eds) Encyclopedia of geochemistry. Kluwer Academic Publishers, Dordrecht/Boston/London, p 219
Barnes S-J, Naldrett AJ, Gorton MP (1985) The origin of the fractionation of platinum-group elements in terrestrial magmas. Chem Geol 53(3–4):303–323
Becker H, Horan MF, Walker RJ, Gao S, Lorand J-P, Rudnick RL (2006) Highly siderophile element composition of the Earth’s primitive upper mantle: constraints from new data on peridotite massifs and xenoliths. Geochim Cosmochim Acta 70(17):4528–4550
Bermingham KR, Walker RJ, Worsham EA (2016) Refinement of high precision Ru isotope analysis using negative thermal ionization mass spectrometry. Int J Mass Spectrom 403:15–26
Borisov A, Palme H (1995) The solubility of iridium in silicate melts: new data from experiments with Ir10Pt90 alloys. Geochim Cosmochim Acta 59(3):481–485
Borisov A, Palme H, Spettel B (1994) Solubility of palladium in silicate melts: implications for core formation in the Earth. Geochim Cosmochim Acta 58(2):705–716
Brandon AD, Walker RJ, Puchtel IS (2006) Platinum-osmium isotope evolution of the Earth’s mantle: constraints from chondrites and Os-rich alloys. Geochim Cosmochim Acta 70(8):2093–2103
Brenan JM, McDonough WF, Dalpé C (2003) Experimental constraints on the partitioning of rhenium and some platinum-group elements between olivine and silicate melt. Earth Planet Sci Lett 212(1–2):135–150
Brenan JM, Finnigan CF, McDonough WF, Homolova V (2012) Experimental constraints on the partitioning of Ru, Rh, Ir, Pt and Pd between chromite and silicate melt: the importance of ferric iron. Chem Geol 302–303:16–32
Brenan JM, Bennett NR, Zajacz Z (2016) Experimental results on fractionation of the Highly Siderophile Elements (HSE) at variable pressures and temperatures during planetary and magmatic differentiation. Rev Mineral Geochem 81(1):1–87
Carlson RW (2005) Application of the Pt-Re-Os isotopic systems to mantle geochemistry and geochronology. Lithos 82(3–4):249–272
Chen JH, Papanastassiou DA, Wasserburg GJ (2010) Ruthenium endemic isotope effects in chondrites and differentiated meteorites. Geochim Cosmochim Acta 74(13):3851–3862
Chou C-L, Shaw DM, Crocket JH (1983) Siderophile trace elements in the Earth’s oceanic crust and upper mantle. J Geophys Res 88(S2):A507–A518
Creaser RA, Papanastassiou DA, Wasserburg GJ (1991) Negative thermal ion mass-spectrometry of osmium, rhenium, and iridium. Geochim Cosmochim Acta 55(1):397–401
Fischer-Gödde M, Becker H, Wombacher F (2011) Rhodium, gold and other highly siderophile elements in orogenic peridotites and peridotite xenoliths. Chem Geol 280(3–4):365–383
Fischer-Gödde M, Burkhardt C, Kruijer TS, Kleine T (2015) Ru isotope heterogeneity in the solar protoplanetary disk. Geochim Cosmochim Acta 168:151–171
Fleet ME, Crocket JH, Liu M, Stone WE (1999) Laboratory partitioning of platinum-group elements (PGE) and gold with application to magmatic sulfide-PGE deposits. Lithos 47(1–2):127–142
Fujii T, Moynier F, Telouk P, Albarède F (2006) Mass-independent isotope fractionation of molybdenum and ruthenium and the origin of isotopic anomalies in Murchison. Astrophys J 647(2):1506
Gelinas A, Kring DA, Zurcher L, Urrutia-Fucugauchi J, Morton O, Walker RJ (2004) Osmium isotope constraints on the proportion of bolide component in Chicxulub impact melt rocks. Meteorit Planet Sci 39(6):1003–1008
Greenfield S (1994) Inductively coupled plasmas in atomic fluorescence spectrometry. A review. J Anal At Spectrom 9(5):565–592
Jones JH, Drake MJ (1986) Geochemical constraints on core formation in the Earth. Nature 322(6076):221–228
Keays RR (1995) The role of komatiitic and picritic magmatism and S-saturation in the formation of ore deposits. Lithos 34(1–3):1–18
Lee SR, Horton JW, Walker RJ (2006) Confirmation of a meteoritic component in impact-melt rocks of the Chesapeake Bay impact structure, Virginia, USA – evidence from osmium isotopic and PGE systematics. Meteorit Planet Sci 41(6):819–833
Lewis W (1753) Experimental examination of a white metallic substance said to be found in the gold mines of the Spanish West Indies, and is there known by the appellations of platina, platina di Pinto, Juan Blanca. Philos Trans R Soc 48:638–689
Lewis W (1757) Experimental examination of platina. Philos Trans R Soc 50:156–166
Li J, Agee CB (1996) Geochemistry of mantle-core differentiation at high pressure. Nature 381(6584):686–689
Lorand J-P, Alard O (2001) Platinum-group element abundances in the upper mantle: new constraints from in situ and whole-rock analyses of Massif Central xenoliths (France). Geochim Cosmochim Acta 65(16):2789–2806
Luguet A, Shirey SB, Lorand J-P, Horan MF, Carlson RW (2007) Residual platinum-group minerals from highly depleted harzburgites of the Lherz massif (France) and their role in HSE fractionation of the mantle. Geochim Cosmochim Acta 71(12):3082–3097
Maier WD (2005) Platinum-group element (PGE) deposits and occurrences: mineralization styles, genetic concepts, and exploration criteria. J Afr Earth Sci 41(3):165–191
McDonald D, Hunt LB (1982) A history of platinum and its allied metals. Johnson-Matthey, London
Morgan JW (1985) Osmium isotope constraints on Earth’s late accretionary history. Nature 317(6039):703–705
Morgan JW (1986) Ultramafic xenoliths: clues to Earth’s late accretionary history. J Geophys Res 91(B12):12375–12387
Mungall JE, Naldrett AJ (2008) Ore deposits of the platinum-group elements. Elements 4(4):253–258
Naldrett T, Kinnaird J, Wilson A, Chunnett G (2008) Concentration of PGE in the Earth’s crust with special reference to the Bushveld complex. Earth Science Frontiers 15(5):264–297
Puchtel IS, Humayun M (2000) Platinum group elements in Kostomuksha komatiites and basalts: implications for oceanic crust recycling and core-mantle interaction. Geochim Cosmochim Acta 64(24):4227–4242
Puchtel IS, Humayun M (2001) Platinum group element fractionation in a komatiitic basalt lava lake. Geochim Cosmochim Acta 17(65):2979–2993
Puchtel IS, Humayun M, Campbell A, Sproule R, Lesher CM (2004) Platinum group element geochemistry of komatiites from the Alexo and Pyke Hill areas, Ontario, Canada. Geochim Cosmochim Acta 68(6):1361–1383
Puchtel IS, Walker RJ, James OB, Kring DA (2008) Osmium isotope and highly siderophile element systematics of lunar impact melt breccias: implications for the late accretion history of the Moon and Earth. Geochim Cosmochim Acta 72(12):3022–3042
Puchtel IS, Walker RJ, Brandon AD, Nisbet EG (2009) Pt-Re-Os and Sm-Nd isotope and HSE and REE systematics of the 2.7 Ga Belingwe and Abitibi komatiites. Geochim Cosmochim Acta 73(20):6367–6389
Puchtel IS, Walker RJ, Touboul M, Nisbet EG, Byerly GR (2014) Insights into early Earth from the Pt-Re-Os isotope and highly siderophile element abundance systematics of Barberton komatiites. Geochim Cosmochim Acta 125:394–413
Rauch S, Morrison GM (2008) Environmental relevance of the platinum-group elements. Elements 4(4):259–263
Rehkämper M, Halliday AN, Fitton JG, Lee D-C, Wieneke M, Arndt NT (1999) Ir, Ru, Pt and Pd in basalts and komatiites: new constraints for the geochemical behavior of the platinum group elements in the mantle. Geochim Cosmochim Acta 63(22):3915–3934
Righter K, Drake MJ (1997) Metal-silicate equilibrium in a homogeneously accreting earth: new results for Re. Earth Planet Sci Lett 146(3–4):541–553
Sharp M, Gerasimenko I, Loudin LC, Liu J, James OB, Puchtel IS, Walker RJ (2014) Characterization of the dominant impactor signature for Apollo 17 impact melt rocks. Geochim Cosmochim Acta 131:62–80
Shirey SB, Walker RJ (1998) The Re-Os isotope system in cosmochemistry and high-temperature geochemistry. Annu Rev Earth Planet Sci 26:423–500
Tennant S (1804) On two metals, found in the black powder remaining after the solution of platina. Philos Trans R Soc Lond 94:411–418
Völkening J, Walczyk T, Heumann KG (1991) Osmium isotope ratio determinations by negative thermal ionization mass spectrometry. Int J Mass Spectrom Ion Process 105(2):147–159
Walker RJ (2009) Highly siderophile elements in the Earth, Moon and Mars: update and implications for planetary accretion and differentiation. Chem Erde-Geochem 69(2):101–125
Walker RJ, Morgan JW, Beary ES, Smoliar MI, Czamanske GK, Horan MF (1997) Applications of the 190Pt-186Os isotope system to geochemistry and cosmochemistry. Geochim Cosmochim Acta 61(22):4799–4807
Walker RJ, Bermingham K, Liu J, Puchtel IS, Touboul M, Worsham EA (2015) In search of late-stage planetary building blocks. Chem Geol 411:125–142
Wollaston WH (1805) On the discovery of palladium; with observations on other substances found with platina. Philos Trans R Soc Lond 95:316–330
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Puchtel, I.S. (2018). Platinum Group Elements. In: White, W.M. (eds) Encyclopedia of Geochemistry. Encyclopedia of Earth Sciences Series. Springer, Cham. https://doi.org/10.1007/978-3-319-39312-4_274
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