Abstract
Due to rapid industrialization and modernization, degradation in the quality of natural and man-made water bodies has become rampant today. The detrimental effects of water contamination have led to substantial economic, social, and health impacts. In water remediation applications, the large family of graphene-based nanomaterials (GBNs) including graphene (G), graphene oxide (GO), and reduced graphene oxide (rGO) have been explored as a promising solution. In the mitigation of various pollutants, which also extends to the mitigation of bacteria/microbial infestation, various modified GBNs have been proposed. The growing field of polluted water bodies management includes adsorption and photocatalytic degradation, among the different technologies developed. In the present chapter, a comprehensive discussion on the recent assessment of GBN for the adsorption and photodegradation of certain pollutants, such as organic dyes, heavy metals, emerging contaminants, and oil have been presented. Efforts have also been made to collate the application of several photocatalytic antibacterial disinfections using GBNs published in recent years. Finally, by paying specific attention to the opportunities and challenges that lie ahead, we address the prospects of GBNs. The authors humbly believe that this write-up will at least provide a general understanding of GBNs in the application of water remediation.
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Abbreviations
- 3D:
-
Three-dimensional
- CB:
-
Conduction band
- G:
-
Graphene
- GBN:
-
Graphene-based nanomaterial
- GO:
-
Graphene oxide
- IPD:
-
Intraparticle diffusion
- MGO:
-
Magnetic graphene oxide
- NP:
-
Nanoparticle
- PFO:
-
Pseudo-first order
- PSO:
-
Pseudo-second order
- rGH:
-
Reduced graphene hydrogel
- rGO:
-
Reduced graphene oxide
- ROS:
-
Reactive oxygen species
- TC:
-
Tetracycline
- VB:
-
Valence band
References
Abd-Elhamid AI, Kamoun EA, El-shanshory AA et al (2019) Evaluation of graphene oxide-activated carbon as effective composite adsorbent toward the removal of cationic dyes: composite preparation, characterization and adsorption parameters. J Mol Liq 279:530–539. https://doi.org/10.1016/j.molliq.2019.01.162
Abdi G, Alizadeh A, Amirian J et al (2019) Polyamine-modified magnetic graphene oxide surface: feasible adsorbent for removal of dyes. J Mol Liq 289:111118. https://doi.org/10.1016/j.molliq.2019.111118
Anuma S, Mishra P, Bhat BR (2021) Polypyrrole functionalized cobalt oxide graphene (COPYGO) nanocomposite for the efficient removal of dyes and heavy metal pollutants from aqueous effluents. J Hazard Mater 416:125929. https://doi.org/10.1016/j.jhazmat.2021.125929
Anwer H, Mahmood A, Lee J et al (2019) Photocatalysts for degradation of dyes in industrial effluents: opportunities and challenges. Nano Res 12:955–972
Arias FA, Guevara M, Tene T et al (2020) The adsorption of methylene blue on eco-friendly reduced graphene oxide. Nano 10:1–18. https://doi.org/10.3390/nano10040681
Baig N, Ihsanullah SM, Saleh TA (2019) Graphene-based adsorbents for the removal of toxic organic pollutants: a review. J Environ Manag 244:370–382. https://doi.org/10.1016/j.jenvman.2019.05.047
Boruah PK, Das MR (2020) Dual responsive magnetic Fe3O4-TiO2/graphene nanocomposite as an artificial nanozyme for the colorimetric detection and photodegradation of pesticide in an aqueous medium. J Hazard Mater 385:121516. https://doi.org/10.1016/j.jhazmat.2019.121516
Bu J, Yuan L, Zhang N et al (2020) High-efficiency adsorption of methylene blue dye from wastewater by a thiosemicarbazide functionalized graphene oxide composite. Diam Relat Mater 101:107604. https://doi.org/10.1016/j.diamond.2019.107604
Chang Z, Chen Y, Tang S et al (2020) Construction of chitosan/polyacrylate/graphene oxide composite physical hydrogel by semi-dissolution/acidification/sol-gel transition method and its simultaneous cationic and anionic dye adsorption properties. Carbohydr Polym 229:115431. https://doi.org/10.1016/j.carbpol.2019.115431
Chávez AM, SolÃs RR, Beltrán FJ (2020) Magnetic graphene TiO2-based photocatalyst for the removal of pollutants of emerging concern in water by simulated sunlight aided photocatalytic ozonation. Appl Catal B Environ 262:118275. https://doi.org/10.1016/j.apcatb.2019.118275
Chen Y, Wang P, Liang Y et al (2019) Fabrication of a three-dimensional porous Z-scheme silver/silver bromide/graphitic carbon nitride@nitrogen-doped graphene aerogel with enhanced visible-light photocatalytic and antibacterial activities. J Colloid Interface Sci 536:389–398. https://doi.org/10.1016/j.jcis.2018.10.061
Coros M, Socaci C, Pruneanu S et al (2020) Thermally reduced graphene oxide as green and easily available adsorbent for sunset yellow decontamination. Environ Res 182:109047. https://doi.org/10.1016/j.envres.2019.109047
Cui B, Wang J h, le Fan L et al (2020) Visible light responsive Bi2S3-graphene/TiO2 nanocomposites: one pot-hydrothermal synthesize and improved photocatalytic properties. Fullerenes Nanotubes Carbon Nanostruct 0:1–9. https://doi.org/10.1080/1536383X.2020.1711516
Diao S, Liu H, Chen S et al (2020) Oil adsorption performance of graphene aerogels. J Mater Sci 55:4578–4591. https://doi.org/10.1007/s10853-019-04292-z
DÃez N, Sliwak A, Gryglewicz S et al (2015) Enhanced reduction of graphene oxide by high-pressure hydrothermal treatment. RSC Adv 5:81831–81837. https://doi.org/10.1039/c5ra14461b
Ding Y, Tian Z, Li H, Wang X (2019) Efficient removal of organic dyes using a three-dimensional graphene aerogel with excellent recycling stability. New Carbon Mater 34:315–324. https://doi.org/10.1016/s1872-5805(19)30020-4
Fadlalla MI, Kumar PS, Selvam V, Babu SG (2020) Emerging energy and environmental application of graphene and their composites: a review. J Mater Sci 55:7156–7183. https://doi.org/10.1007/s10853-020-04474-0
Fan H, Zhao C, Liu S, Shen H (2017) Adsorption characteristics of chlorophenols from aqueous solution onto graphene. J Chem Eng Data 62:1099–1105. https://doi.org/10.1021/acs.jced.6b00918
Gaber D, Haija MA, Eskhan A (2017) Graphene as an efficient and reusable adsorbent compared to activated carbons for the removal of phenol from aqueous solutions. Water Air Soil Pollut 228:1–14. https://doi.org/10.1007/s11270-017-3499-x
Gunnagol RM, Rabinal MHK (2019) TiO2/rGO/CuS nanocomposites for efficient photocatalytic degradation of rhodamine-B dye. ChemistrySelect 4:6167–6176. https://doi.org/10.1002/slct.201901041
Hegab HM, Elmekawy A, Zou L et al (2016) The controversial antibacterial activity of graphene-based materials. Carbon N Y 105:362–376. https://doi.org/10.1016/j.carbon.2016.04.046
Hiew BYZ, Lee LY, Lee XJ et al (2018) Review on synthesis of 3D graphene-based configurations and their adsorption performance for hazardous water pollutants. Process Saf Environ Prot 116:262–286. https://doi.org/10.1016/j.psep.2018.02.010
Hu K, **e X, Szkopek T, Cerruti M (2016) Understanding hydrothermally reduced graphene oxide hydrogels: from reaction products to hydrogel properties. Chem Mater 28:1756–1768. https://doi.org/10.1021/acs.chemmater.5b04713
Huang D, Wu J, Wang L et al (2019) Novel insight into adsorption and co-adsorption of heavy metal ions and an organic pollutant by magnetic graphene nanomaterials in water. Chem Eng J 358:1399–1409. https://doi.org/10.1016/j.cej.2018.10.138
Huang J, Yan Z (2018) Adsorption mechanism of oil by resilient graphene aerogels from oil-water emulsion. Langmuir 34:1890–1898. https://doi.org/10.1021/acs.langmuir.7b03866
Huo J, Yu G, Wang J (2021) Adsorptive removal of Sr(II) from aqueous solution by polyvinyl alcohol/graphene oxide aerogel. Chemosphere 278:130492. https://doi.org/10.1016/j.chemosphere.2021.130492
Ji L, Liu B, Qian Y et al (2020) Enhanced visible-light-induced photocatalytic disinfection of Escherichia coli by ternary Bi2WO6/TiO2/reduced graphene oxide composite materials: insight into the underlying mechanism. Adv Powder Technol 31:128–138. https://doi.org/10.1016/j.apt.2019.10.005
Konios D, Stylianakis MM, Stratakis E, Kymakis E (2014) Dispersion behaviour of graphene oxide and reduced graphene oxide. J Colloid Interface Sci 430:108–112. https://doi.org/10.1016/j.jcis.2014.05.033
Kyzas GZ, Kostoglou M (2014) Green adsorbents for wastewaters: a critical review. Materials (Basel) 7:333–364. https://doi.org/10.3390/ma7010333
Lai KC, Lee LY, Hiew BYZ et al (2019) Environmental application of three-dimensional graphene materials as adsorbents for dyes and heavy metals: review on ice-templating method and adsorption mechanisms. J Environ Sci 79:174–199. https://doi.org/10.1016/j.jes.2018.11.023
Lau GE, Che Abdullah CA, Wan Ahmad WAN et al (2020) Eco-friendly photocatalysts for degradation of dyes. Catalysts 10:1129. https://doi.org/10.3390/catal10101129
Li G, Wu Y, Zhang M et al (2019) Enhanced removal of toxic Cr(VI) in wastewater by synthetic TiO2/g-C3N4 microspheres/rGO Photocatalyst under irradiation of visible light. Ind Eng Chem Res 58:8979–8989. https://doi.org/10.1021/acs.iecr.8b05990
Li R, Lai L, Su S et al (2020) One-step facile hydrothermal synthesis of heteroatom-doped porous graphene reduced comparatively by different reductants for high performance supercapacitors. Mater Today Commun 101128. https://doi.org/10.1016/j.mtcomm.2020.101128
Liu G, Yu R, Lan T, Liu Z (2019) Gallic acid-functionalized graphene hydrogel as adsorbent for removal of chromium (III) and organic dye pollutants from tannery wastewater. RSC Adv 9:27060–27068. https://doi.org/10.1039/c9ra05664e
Liu Y, Men B, Hu A et al (2020) Facile synthesis of graphene-based hyper-cross-linked porous carbon composite with superior adsorption capability for chlorophenols. J Environ Sci 90:395–407. https://doi.org/10.1016/j.jes.2019.11.018
Lu W, Dai Z, Li L et al (2020) Preparation of composite hydrogel (PCG) and its adsorption performance for uranium(VI). J Mol Liq 303:112604. https://doi.org/10.1016/j.molliq.2020.112604
Ma X, **ang Q, Liao Y et al (2018) Visible-light-driven CdSe quantum dots/graphene/TiO2 nanosheets composite with excellent photocatalytic activity for E. coli disinfection and organic pollutant degradation. Appl Surf Sci 457:846–855. https://doi.org/10.1016/j.apsusc.2018.07.003
Mao B, Sidhureddy B, Thiruppathi AR et al (2020) Efficient dye removal and separation based on graphene oxide nanomaterials. New J Chem 44:4519–4528. https://doi.org/10.1039/c9nj05895h
Menazea AA, Ahmed MK (2020) Silver and copper oxide nanoparticles-decorated graphene oxide via pulsed laser ablation technique: preparation, characterization, and photoactivated antibacterial activity. Nano-Struct Nano-Objects 22:100464. https://doi.org/10.1016/j.nanoso.2020.100464
Miao J, Wang F, Chen Y et al (2019) The adsorption performance of tetracyclines on magnetic graphene oxide: a novel antibiotics absorbent. Appl Surf Sci 475:549–558. https://doi.org/10.1016/j.apsusc.2019.01.036
Mukherjee M, Goswami S, Banerjee P et al (2019) Ultrasonic assisted graphene oxide nanosheet for the removal of phenol containing solution. Environ Technol Innov 13:398–407. https://doi.org/10.1016/j.eti.2016.11.006
Navarro CB, Coronado E, Marti-Gastaldo C et al (2012) Influence of the pH on the synthesis of reduced graphene oxide under. Nanoscale 4:3977–3982. https://doi.org/10.1039/c2nr30605k
Nguyen DCT, Cho KY, Oh WC (2019) Mesoporous CuO-graphene coating of mesoporous TiO2 for enhanced visible-light photocatalytic activity of organic dyes. Sep Purif Technol 211:646–657. https://doi.org/10.1016/j.seppur.2018.10.009
Noreen Z, Khalid NR, Abbasi R et al (2019) Visible light sensitive Ag/TiO2/graphene composite as a potential coating material for control of Campylobacter jejuni. Mater Sci Eng C 98:125–133. https://doi.org/10.1016/j.msec.2018.12.087
Raizada P, Sudhaik A, Singh P (2019) Photocatalytic water decontamination using graphene and ZnO coupled photocatalysts: a review. Mater Sci Energy Technol 2:509–525. https://doi.org/10.1016/j.mset.2019.04.007
Ranjith R, Renganathan V, Chen SM et al (2019) Green synthesis of reduced graphene oxide supported TiO2/Co3O4 nanocomposite for photocatalytic degradation of methylene blue and crystal violet. Ceram Int 45:12926–12933. https://doi.org/10.1016/j.ceramint.2019.03.219
Shandilya P, Mittal D, Soni M, Raizada P (2018) Fabrication of fluorine doped graphene and SmVO4 based dispersed and adsorptive photocatalyst for abatement of phenolic compounds from water and bacterial disinfection. J Clean Prod 203:386–399. https://doi.org/10.1016/j.jclepro.2018.08.271
Smith AT, Marie A, Zeng S et al (2019) Synthesis, properties, and applications of graphene oxide/ reduced graphene oxide and their nanocomposites. Nano Mater Sci 1:31–47. https://doi.org/10.1016/j.nanoms.2019.02.004
Sun Y, Chen L, Yu J et al (2020) Lightweight graphene oxide-based sponges with high compressibility and durability for dye adsorption. Carbon N Y 160:54–63. https://doi.org/10.1016/j.carbon.2020.01.009
Sun Z, Zhao L, Liu C et al (2019) A novel 3D adsorbent of reduced graphene oxide-β-cyclodextrin aerogel coupled hardness with softness for efficient removal of bisphenol A. Chem Eng J 372:896–904. https://doi.org/10.1016/j.cej.2019.04.217
Tabish TA, Memon FA, Gomez DE et al (2018) A facile synthesis of porous graphene for efficient water and wastewater treatment. Sci Rep 8:1–14. https://doi.org/10.1038/s41598-018-19978-8
Tan J, Wang X, Hou W et al (2019) Fabrication of Fe3O4@graphene/TiO2 nanohybrid with enhanced photocatalytic activity for isopropanol degradation. J Alloys Compd 792:918–927. https://doi.org/10.1016/j.jallcom.2019.03.378
Tang B, Chen H, Peng H et al (2018) Graphene modified tio2 composite photocatalysts: mechanism, progress and perspective. Nano 8:27–30. https://doi.org/10.3390/nano8020105
Tene T, Usca GT, Guevara M et al (2020) Toward large-scale production of oxidized graphene. Nano 10:1–11. https://doi.org/10.3390/nano10020279
Tran HN, You SJ, Hosseini-Bandegharaei A, Chao HP (2017) Mistakes and inconsistencies regarding adsorption of contaminants from aqueous solutions: a critical review. Water Res 120:88–116. https://doi.org/10.1016/j.watres.2017.04.014
Wan W, Zhang F, Yu S et al (2016) Hydrothermal formation of graphene aerogel for oil sorption: the role of reducing agent, reaction time and temperature. New J Chem 40:3040–3046. https://doi.org/10.1039/C5NJ03086B
Wang H, Wang C, Liu S et al (2019a) Superhydrophobic and superoleophilic graphene aerogel for adsorption of oil pollutants from water. RSC Adv 9:8569–8574. https://doi.org/10.1039/c9ra00279k
Wang W, Gong Q, Chen Z et al (2019b) Adsorption and competition investigation of phenolic compounds on the solid-liquid interface of three-dimensional foam-like graphene oxide. Chem Eng J 378:122085. https://doi.org/10.1016/j.cej.2019.122085
Wang X, Hu Y, Min J et al (2018) Adsorption characteristics of phenolic compounds on graphene oxide and reduced graphene oxide: a batch experiment combined theory calculation. Appl Sci 8:1950. https://doi.org/10.3390/app8101950
**n X, Li S, Zhang N et al (2019) 3D graphene/AgBr/Ag cascade aerogel for efficient photocatalytic disinfection. Appl Catal B Environ 245:343–350. https://doi.org/10.1016/j.apcatb.2018.12.066
Xu L, Yang L, Bai X et al (2019) Persulfate activation towards organic decomposition and Cr (VI) reduction achieved by a novel CQDs-TiO2−x/rGO nanocomposite. Chem Eng J 373:238–250. https://doi.org/10.1016/j.cej.2019.05.028
Xu Y, Sheng K, Li C, Shi G (2010) Self-assembled graphene hydrogel. ACS Nano 4:4324–4330. https://doi.org/10.1021/nn101187z
Xue L, An F, Yang Y, Ma Y (2020) Synthesis of N-TiO2/BiOI/RGO composites with significantly enhanced visible light photocatalytic activity. J Mater Res 35:153–161. https://doi.org/10.1557/jmr.2019.401
Yan M, Huang W, Li Z (2019) Chitosan cross-linked graphene oxide/ lignosulfonate composite aerogel for enhanced adsorption of methylene blue in water. Int J Biol Macromol 136:927–935. https://doi.org/10.1016/j.ijbiomac.2019.06.144
Yang H, Zhang T, Jiang M et al (2015) Ambient pressure dried graphene aerogels with superelasticity and multifunctionality. J Mater Chem A 3:19268–19272. https://doi.org/10.1039/C5TA06452J
Yao T, Qiao L, Du K (2020) High tough and highly porous graphene/carbon nanotubes hybrid beads enhanced by carbonized polyacrylonitrile for efficient dyes adsorption. Microporous Mesoporous Mater 292:109716. https://doi.org/10.1016/j.micromeso.2019.109716
Yu F, Sun Y, Yang M, Ma J (2019a) Adsorption mechanism and effect of moisture contents on ciprofloxacin removal by three-dimensional porous graphene hydrogel. J Hazard Mater 374:195–202. https://doi.org/10.1016/j.jhazmat.2019.04.021
Yu S, Wei D, Shi L et al (2019b) Three-dimensional graphene/titanium dioxide composite for enhanced U(VI) capture: insights from batch experiments, XPS spectroscopy and DFT calculation. Environ Pollut 251:975–983. https://doi.org/10.1016/j.envpol.2019.04.127
Zarrin S, Heshmatpour F (2020) Facile preparation of new nanohybrids for enhancing photocatalytic activity toward removal of organic dyes under visible light irradiation. J Phys Chem Solids 140:109271. https://doi.org/10.1016/j.jpcs.2019.109271
Zeng T, Yu Y, Li Z et al (2019) 3D MnO2 nanotubes@reduced graphene oxide hydrogel as reusable adsorbent for the removal of heavy metal ions. Mater Chem Phys 231:105–108. https://doi.org/10.1016/j.matchemphys.2019.04.019
Zhang J, Zhu S, Song K et al (2020) 3D reduced graphene oxide hybrid nano-copper scaffolds with a high antibacterial performance. Mater Lett 267:127527. https://doi.org/10.1016/j.matlet.2020.127527
Zhao Y, Sun T, Liao W et al (2019) Amphiphilic graphene aerogel with high oil and water adsorption capacity and high contact area for interface reaction. ACS Appl Mater Interfaces 11:22794–22800. https://doi.org/10.1021/acsami.9b06506
Zheng ALT, Andou Y (2021) Detection and remediation of bisphenol A (BPA) using graphene-based materials: mini-review. Int J Environ Sci Technol. https://doi.org/10.1007/s13762-021-03512-x
Zheng ALT, Boonyuen S, Li GY et al (2021a) Design of reduced graphene hydrogel with alkylamine surface functionalization through immersion/agitation method and its adsorption mechanism. J Mol Struct 131008. https://doi.org/10.1016/j.molstruc.2021.131008
Zheng ALT, Boonyuen S, Ohno T, Andou Y (2021b) Accessing effects of aliphatic dicarboxylic acid towards the physical and chemical changes in low temperature hydrothermally reduced graphene hydrogel. J Porous Mater. https://doi.org/10.1007/s10934-021-01072-6
Zheng ALT, Boonyuen S, Ohno T, Andou Y (2021c) Hydrothermally reduced graphene hydrogel intercalated with divalent ions for dye adsorption studies. PRO 9:169. https://doi.org/10.3390/pr9010169
Zheng ALT, Farrag HN, Sabidi S et al (2021d) Accessing the anti-microbial activity of cyclic peptide immobilized on reduced graphene oxide. Mater Lett 304:130621. https://doi.org/10.1016/j.matlet.2021.130621
Zheng ALT, Phromsatit T, Boonyuen S, Andou Y (2020) Synthesis of silver nanoparticles /porphyrin/reduced graphene oxide hydrogel as dye adsorbent for wastewater treatment. FlatChem:100174. https://doi.org/10.1016/j.flatc.2020.100174
Zheng ALT, Sabidi S, Ohno T et al (2022a) Cu2O/TiO2 decorated on cellulose nanofiber/reduced graphene hydrogel for enhanced photocatalytic activity and its antibacterial applications. Chemosphere 286:131731. https://doi.org/10.1016/j.chemosphere.2021.131731
Zheng ALT, Ohno T, Andou Y (2022b) Recent progress in photocatalytic efficiency of hybrid three-dimensional (3D) graphene architectures for pollution remediation. Top Catal 65:1634–1647. https://doi.org/10.1007/s11244-022-01610-9
Zhu J, Zhang H, Chen R et al (2019) An anti-algae adsorbent for uranium extraction: L-Arginine functionalized graphene hydrogel loaded with Ag nanoparticles. J Colloid Interface Sci 543:192–200. https://doi.org/10.1016/j.jcis.2019.02.045
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Zheng, A.L.T., Che Abdullah, C.A., Andou, Y. (2023). Graphene-Based Nanomaterials for Water Remediation Applications. In: Shanker, U., Hussain, C.M., Rani, M. (eds) Handbook of Green and Sustainable Nanotechnology. Springer, Cham. https://doi.org/10.1007/978-3-031-16101-8_36
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