Amino Acid Racemization

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Encyclopedia of Geoarchaeology

Part of the book series: Encyclopedia of Earth Sciences Series ((EESS))

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Synonyms

Amino acid geochronology; Amino acid racemization; Aminostratigraphy

Definitions

Amino acid racemization: a spontaneous reaction describing the interconversion between the chiral forms of an amino acid.

Chiral: describes molecules that may exist as mirror images of themselves that are nonsuperimposable; such molecules exhibit chirality.

Enantiomer: one of a pair of nonsuperimposable mirror images; also called an optical isomer.

Stereoisomer: molecules that possess the same elemental composition but different three-dimensional arrangements of atoms.

Diastereomer: a stereoisomer that is not a mirror image, that is, not an enantiomer.

Amino acids are the building blocks of proteins. They are found in all living tissues and can be preserved in fossil biominerals such as bone, teeth, and shells. The 20 naturally occurring amino acids all have a central carbon atom (the α-C) with four attached groups: an amino group (NH3), a carboxylic acid group (COOH), hydrogen (H), and a side...

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Bibliography

  • Hare, P. E., and Abelson, P. H., 1968. Racemization of amino acids in fossil shells. Yearbook of the Carnegie Institution of Washington, 66, 526–528.

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  • Parfitt, S. A., Barendregt, R. W., Breda, M., Candy, I., Collins, M. J., Coope, G. R., Durbidge, P., Field, M. H., Lee, J. R., Lister, A. M., Mutch, R., Penkman, K. E. H., Preece, R. C., Rose, J., Stringer, C. B., Symmons, R., Whittaker, J. E., Wymer, J. J., and Stuart, A. J., 2005. The earliest record of human activity in northern Europe. Nature, 438, 1008–1012.

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  • Towe, K. M., 1980. Preserved organic ultrastructure: an unreliable indicator for Paleozoic amino acid biogeochemistry. In Hare, P. E., Hoering, T. C., and King, K., Jr. (eds.), Biogeochemistry of Amino Acids. New York: Wiley, pp. 65–74.

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  • Wehmiller, J. F., 2012. United States Quaternary coastal sequences and molluscan racemization geochronology – what have they meant for each other over the past 45 years? Quaternary Geochronology, doi:10.1016/j.quageo.2012.05.008.

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Correspondence to Kirsty Penkman .

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Penkman, K. (2017). Amino Acid Racemization. In: Gilbert, A.S. (eds) Encyclopedia of Geoarchaeology. Encyclopedia of Earth Sciences Series. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-4409-0_38

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