Definition
SIMS, secondary ion mass spectroscopy, is a surface chemical analysis technique for solid materials. As its name indicates, a specimen is bombarded with a primary ion beam and the secondary ions are collected using a detector – a spectrometer. The secondary ions provide information on the elemental, molecular, and isotopic composition of a material’s surface. SIMS is one of the most sensitive techniques for surface analysis.
Scientific Fundamentals
In 1910, Joseph John Thomson, a British physicist, observed the emission of secondary ions followed by the bombardment of a metal surface (Thomson 1910). It took almost 30 years after his observation to enable the qualitative and quantitative analysis of secondary ions. In 1949, Herzog and Vieböck built the first prototype of SIMS and analyzed secondary ions from metals and oxides (Herzog and Vieböck 1949). It was in the 1960s that two types of practical SIMS were developed: one by Castaing and Slodzian in 1960 and another by...
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
C.A. Andersen, Analytic methods for the ion microprobe mass analyzer. Part II. Int. J. Mass Spectrom. Ion Phys. 3, 413 (1970)
C.A. Andersen, J.R. Hinthorne, Ion microprobe mass analyzer. Science 175, 853 (1972)
H.H. Anderson, H.L. Bay, Sputtering by particle bombardment І, in Topics in Applied Physics, ed. by R. Behrisch (Springer, Berlin, 1981), p. 145
A. Benninghoven, Developments in secondary ion mass spectroscopy and applications to surface studies. Surf. Sci. 53, 596 (1975)
R.F.K. Herzog, F.P. Vieböck, Ion source for mass spectrography. Phys. Rev. 76, 855–856 (1949)
G.M. Lancaster, F. Honda, Y. Fukuda, J.W. Rabalais, Secondary ion mass spectrometry of molecular solids. Cluster formation during ion bombardment of frozen water, benzene, and cyclohexane. J. Am. Chem. Soc. 101(8), 1951 (1979)
J. Maul, K. Wittmaack, Secondary ion emission from silicon and silicon oxide. Surf. Sci. 47, 358 (1975)
D.M. Parkin, The displacement cascade in ceramic oxides. Nucl. Instrum. Methods Phys. Res., Sect. B 46, 26 (1990)
A.L. Pivovarov, F.A. Stevie, D.P. Griffis, Improved charge neutralization method for depth profiling of bulk insulators using O2+ primary beam on a magnetic sector SIMS instrument. Appl. Surf. Sci. 231–232, 786 (2004)
A. Schnieders, Full wafer defect analysis with time-of-flight secondary ion mass spectrometry, in Advanced Semiconductor Manufacturing Conference (ASMC), (San Francisco, CA, 2010), p. 158
H.A. Storms, K.F. Brown, J.D. Stein, Evaluation of a cesium positive ion source for secondary ion mass spectrometry. Anal. Chem. 49(13), 2023 (1977)
J.J. Thomson, Rays of positive electricity. Phil. Mag. 20, 752–767 (1910)
J.W. Valley et al., Ion microprobe analysis of oxygen, carbon, and hydrogen isotope ratios, in Applications of Microanalytical Techniques to Understanding Mineralizing Processes, ed. by M.A. Mckibben et al. Review in Economic Geology, vol. 7 (Society of Economic Geologists, Littleton, 1998), p. 73
J.C. Vickerman, A. Brown, N.M. Reed, in Secondary Ion Mass Spectrometry: Principles and Applications, ed. by R. Breslow (Oxford University Press, Oxford, 1989), p. 10
R.G. Wilson, Surface ionization ion sources. IEEE Trans. Nucl. Sci. 14, 72 (1967)
R.G. Wilson, F.A. Stevie, C.W. Magee, Secondary Ion Mass Spectrometry: A Practical Handbook of Depth Profiling and Bulk Impurity Analysis (Wiley, New York, 1989)
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2013 Springer Science+Business Media New York
About this entry
Cite this entry
Joo, S., Liang, H. (2013). Secondary Ion Mass Spectroscopy (SIMS). In: Wang, Q.J., Chung, YW. (eds) Encyclopedia of Tribology. Springer, Boston, MA. https://doi.org/10.1007/978-0-387-92897-5_1218
Download citation
DOI: https://doi.org/10.1007/978-0-387-92897-5_1218
Publisher Name: Springer, Boston, MA
Print ISBN: 978-0-387-92896-8
Online ISBN: 978-0-387-92897-5
eBook Packages: EngineeringReference Module Computer Science and Engineering