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Raman Spectroscopy of Monolayer and Multilayer Graphenes

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Raman Spectroscopy of Two-Dimensional Materials

Part of the book series: Springer Series in Materials Science ((SSMATERIALS,volume 276))

Abstract

The discovery of monolayer graphene in 2004 has triggered a great effort to investigate the fundamental properties and applications of all two-dimensional materials (2DMs). Monolayer graphene (1LG) can be stacked layer by layer in a particular way (AB, ABC and twist) to form multilayer graphene (MLG), whose properties vary according to the stacking. Raman spectroscopy is a useful tool to reveal the chemical and physical properties of graphene materials. In this chapter, we review the systematic development of the Raman spectroscopy of pristine 1LG and MLG. The essential Raman scattering processes of the entire first and second order modes in intrinsic 1LG are addressed in detail. We further introduce the concept of double resonance Raman scattering in graphene. Moreover, a series of works on the shear (C), layer-breathing (LB) and 2D modes of MLGs with different stacking orders are discussed. Finally, various types of resonance Raman spectroscopy of 1LG and MLG are also presented. The Raman spectroscopy of graphene materials can serve as a typical example in studying the Raman spectroscopy of other 2DMs and introducing the fundamental physical concepts for 2DMs.

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  • 10 March 2019

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Acknowledgements

We acknowledge support from the National Key Research and Development Program of China (Grant No. 2016YFA0301204), the National Natural Science Foundation of China (Grant No. 11474277, 11874350 and 11434010), and the Bei**g Municipal Science and Technology Commission.

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Authors and Affiliations

  1. State Key Laboratory of Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, Bei**g, China

    Jiang-Bin Wu, Miao-Ling Lin & **-Heng Tan

  2. College of Materials Science and Opto-Electronic Technology, University of Chinese Academy of Science, Bei**g, China

    Jiang-Bin Wu & Miao-Ling Lin

  3. Center of Materials Science and Opto-Electronics Engineering & CAS Center of Excellence in Topological Quantum Computation, University of Chinese Academy of Sciences, Bei**g, China

    **-Heng Tan

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  1. Jiang-Bin Wu
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  2. Miao-Ling Lin
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  1. Center of Materials Science and Opto-Electronics Engineering & CAS Center of Excellence in Topological Quantum Computation and University of Chinese Academy of Sciences, State Key Laboratory of Superlattices and Microstructures, Institute of Semiconductors and Chinese Academy of Sciences, Bei**g, China

    **-Heng Tan

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Wu, JB., Lin, ML., Tan, PH. (2019). Raman Spectroscopy of Monolayer and Multilayer Graphenes. In: Tan, PH. (eds) Raman Spectroscopy of Two-Dimensional Materials. Springer Series in Materials Science, vol 276. Springer, Singapore. https://doi.org/10.1007/978-981-13-1828-3_1

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