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Investigation of Hydrogen Sorption Properties of TiMn2 Based Alloys

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Hydrogen Materials Science and Chemistry of Metal Hydrides

Part of the book series: NATO Science Series ((NAII,volume 71))

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Abstract

Microprobe analysis and X-ray powder diffraction were performed for a series of intermetallic compounds Ti0.95Zr0.05Mn1.45M0.5where M = V, Cr, Mn, Co, Ni and Al. These compounds crystallize in the hexagonal C14-type Laves phase. The study of their hydriding properties at 298K shows that the intermetallics based on V and Cr present the best behavior (insertion of 3 H per formula unit and decrease of the plateau pressure around 2.2 and 2.6 MPa respectively). These properties can be explained considering the crystal structure investigation.

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Authors and Affiliations

  1. Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB), CNRS [UPR 9048], Université Bordeaux 1, Avenue du Dr A. Schweitzer, 33608, Pessac Cedex, France

    J-L. Bobet, B. Chevalier & B. Darriet

Authors
  1. J-L. Bobet
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  2. B. Chevalier
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  3. B. Darriet
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Editor information

Editors and Affiliations

  1. Department of Chemistry, University of Central Florida, Orlando, Florida, USA

    Michael D. Hampton

  2. Institute of Hydrogen and Solar Energy, Ukrainian Academy of Sciences, Kiev, Ukraine

    Dmitry V. Schur

  3. Institute for Problems of Materials Science, Ukrainian Academy of Sciences, Kiev, Ukraine

    Svetlana Yu. Zaginaichenko  & V. I. Trefilov  & 

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© 2002 Springer Science+Business Media Dordrecht

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Bobet, JL., Chevalier, B., Darriet, B. (2002). Investigation of Hydrogen Sorption Properties of TiMn2 Based Alloys. In: Hampton, M.D., Schur, D.V., Zaginaichenko, S.Y., Trefilov, V.I. (eds) Hydrogen Materials Science and Chemistry of Metal Hydrides. NATO Science Series, vol 71. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0558-6_13

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  • DOI: https://doi.org/10.1007/978-94-010-0558-6_13

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-0731-6

  • Online ISBN: 978-94-010-0558-6

  • eBook Packages: Springer Book Archive

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