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Electrochemical Route to Fluorinated Kethoesters

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Novel Trends in Electroorganic Synthesis

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Abstract

Electrochemical reduction of organic fluorohalogen compounds in the presence of trimethylchlorosilane enables to obtain the fluorinated silanes in synthetic yields. Trifluoroacetic acid esters at the same conditions forms condensation product — pentafluoroacetoacetic ester.

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References

  1. G.K.S. Prakash, R. Krishnamuri, G.A.Olah, J. Am. Chem. Soc., 1989, 1I1, 2449.

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Author information

Authors and Affiliations

  1. State Research Institute of Organic Chemistry & Technology, 23, Shosse Entuziastov, Moscow, 111024, Russia

    B. I. Martynov

  2. A.N.Nesmeyanov Institute of Organoelement Compounds Russian Academy of Sciences, 28, Vavilov str., Moscow, 117813, Russia

    A. A. Stepanov

Authors
  1. B. I. Martynov
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  2. A. A. Stepanov
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Editor information

Editors and Affiliations

  1. Department of Applied Chemistry, Faculty of Engineering, Okayama University, 3-1-1 Tsushima-naka, 700-8530, Okayama, Japan

    Sigeru Torii

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© 1998 Springer Japan

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Martynov, B.I., Stepanov, A.A. (1998). Electrochemical Route to Fluorinated Kethoesters. In: Torii, S. (eds) Novel Trends in Electroorganic Synthesis. Springer, Tokyo. https://doi.org/10.1007/978-4-431-65924-2_90

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  • DOI: https://doi.org/10.1007/978-4-431-65924-2_90

  • Publisher Name: Springer, Tokyo

  • Print ISBN: 978-4-431-65926-6

  • Online ISBN: 978-4-431-65924-2

  • eBook Packages: Springer Book Archive

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