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57Fe Mössbauer spectroscopic study of (25−x)MnO-xZnO-15Fe2O3-60B2O3 glasses

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NASSAU 2006

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Abstract

The 57Fe Mössbauer technique has been used to investigate the effect of zinc oxide substitution in (25-x)MnO-xZnO-15Fe2O3-60B2O3 glass system (x=0, 5, 10, 15 and 20 mol% of ZnO). Mössbauer absorption spectra for all the samples recorded at room temperature suggest the existence of the two paramagnetic quadrupole doublets. The observed variations in hyperfine parameters have been explained on the basis of cations distribution and exchange interaction at the lattice sites and it is concluded that B-B interaction increases while the metal-metal interaction decreases due to replacement of manganese oxide by zinc oxide. These results suggest that the present glass system exhibits a paramagnetic behaviour that changes towards the weak paramagnetic when manganese oxide was replaced with zinc oxide.

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Author information

Authors and Affiliations

  1. Department of Physics, Kurukshetra University, Kurukshetra, 136 119, India

    Roshan Lal

  2. Department of Physics, Maharshi Dayanand University, Rohtak, 124 001, India

    S. P. Taneja

  3. Department of Chemistry, Nassu Community College, Garden City, NY, USA

    C. Wynter

Authors
  1. Roshan Lal
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  2. S. P. Taneja
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  3. C. Wynter
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Corresponding author

Correspondence to Roshan Lal .

Editor information

Editors and Affiliations

  1. Argonne National Lab, Argonne, IL, USA

    E. E. Alp

  2. Nassau Community College, Garden City, NY, USA

    C. I. Wynter

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Lal, R., Taneja, S.P., Wynter, C. (2007). 57Fe Mössbauer spectroscopic study of (25−x)MnO-xZnO-15Fe2O3-60B2O3 glasses. In: Alp, E.E., Wynter, C.I. (eds) NASSAU 2006. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-71127-8_14

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  • DOI: https://doi.org/10.1007/978-3-540-71127-8_14

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-71124-7

  • Online ISBN: 978-3-540-71127-8

  • eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)

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