Abstract
Experiments were carried out by adding NaF as catalyst in a Ar atmosphere to study the isothermal reduction kinetics of vanadium titano-magnetite carbon composite pellets under high temperature in the range from1473 to 1673K. By analyzing reduction mechanism, it was found that the rate controlling step was gas diffusion, and the activation energy was 178.39kJ•mol-1 without none catalysts. Adding NaF of 3% to vanadium titano-magnetite carbon composite pellets can decrease the apparent activation energy of reduction, and the decrease extent was 15.79kJ•mol-1. In addition, temperature is an important factor influencing on reaction rate.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
References
G.H. Zhang, Z. Yan, and Y.J. Feng, “Reduction Kinetics of Vanadic Titano-magnetite in Panzhihua”, Journal of the Chinese Rare Earth Society, 26 (2008), 210–216.
K.J. Hu, G. **, and J. Yao, “Status Quo of Manufacturing Techniques of Titanium of Titanium Slag in the World”, World Nonferrous Metals, 12 (2006), 26–30.
X. Xue, “Research on Direct Reduction of Vanadic Tianomagetite”, Iron Steel Vandium Titanium, 3 (2007), 37–41.
J. Deng, X. Xue, and G.G. Liu, “Current Situation and Development of Comprehensive Utilization of Vanadium-Bearing Titanomagnetite at Pangang”, Journal of Materials and Metallurgy, 2 (2007), 83–88.
X.M. Yang, Z.C. Guo, and D.G. Wang, “Research on the Reduction Mechanism of Iron Ore Pel lets Containing Graphite”, Engineering Chemistry and Metallurgy, 2 (1995), 118–127.
X.M. Yang, Y.S. **e, and D.G. Wang, “Effect of CaO and CaCO3 on Reduction Rate of Iron Ore Pellets Containing Carbon”., Journal of Iron and Steel, int., 2 (2000), 1–5.
L.H. Zhou, and F.H. Zeng, “Reduction mechanisms of vanadium titano-magnetite-non-coking coal mixed pellet”, Ironmaking and Steelmaking, 1 (2011), 59–64.
G.H. Han, T. Jiang, and Y.B. Zhang, “High-Temperature Oxidation Behavior of Vanadium, Titanium-Bearing Magnetite Pellet”, Journal of Iron and Steel, int., 8 (2011), 14–19.
Author information
Authors and Affiliations
Editor information
Rights and permissions
Copyright information
© 2015 TMS (The Minerals, Metals & Materials Society)
About this paper
Cite this paper
**ang-dong, X., Jian-liang, Z., **ng-le, L., Zhen-yang, W., Ke-xin, J. (2015). Strengthen Reduction Process of Vanadium Titano-Magnetite Adding NaF Under High Temerature. In: TMS 2015 144th Annual Meeting & Exhibition. Springer, Cham. https://doi.org/10.1007/978-3-319-48127-2_110
Download citation
DOI: https://doi.org/10.1007/978-3-319-48127-2_110
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-48608-6
Online ISBN: 978-3-319-48127-2
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)