Abstract
Ion-exchange resins (IERs) possess the capability of catalyzing several classes of reactions, apart from their ability to make separations. In fact, it is possible to synthesize tailor-made IERs for the reactive processes at hand. Use of IERs can fetch a number of advantages compared to those of homogeneous catalysts and other solid catalysts. Reactive separation (RS) is a relatively new process technology that has the potential to offer several advantages over the conventional approach of reaction followed by separation. Various separation steps can be coupled with the reaction, including: distillation, extraction, chromatography, crystallization and separation by membranes. This chapter reviews the salient features and industrial applications of reactive separations using IERs.
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Abbreviations
- A-15:
-
Amberlyst 15
- AEM:
-
Anion-exchange membrane
- CD:
-
Catalytic distillation
- CEM:
-
Cation-exchange membrane
- CSTR:
-
Continuous stirred tank reactor
- FBCR:
-
Fixed bed chromatographic reactor
- GCE:
-
Green chemistry and engineering
- IER:
-
Ion-exchange resin
- LAB sulphonate:
-
Linear alkyl-benzene sulfonate
- LPG:
-
Liquefied petroleum gas
- PI:
-
Process intensification
- RA:
-
Reactive absorption
- RC:
-
Reactive chromatography
- RCond:
-
Reactive condensation
- RCr:
-
Reactive crystallization
- RD:
-
Reactive distillation
- RM:
-
Reactive membrane
- RPr:
-
Reactive precipitation
- RS:
-
Reactive separation
- RStr:
-
Reactive strip**
- SCMCR:
-
Simulated counter current moving bed chromatographic reactor
- SMBR:
-
Simulated moving-bed reactor
- UO:
-
Unit operations
- UP:
-
Unit processes
- VLE:
-
Vapor–liquid equilibrium
- VLLE:
-
Vapor–liquid–liquid equilibrium
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Shetty, A.V., Mahajan, Y.S. (2019). Chromatographic Reactive Separations. In: Inamuddin, Rangreez, T., M. Asiri, A. (eds) Applications of Ion Exchange Materials in Chemical and Food Industries. Springer, Cham. https://doi.org/10.1007/978-3-030-06085-5_7
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