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New Sorbents for Thin-Layer Chromatography

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Recent Advances in Thin-Layer Chromatography

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Summary

The chromatographic and physical properties of surface-modified pre-coated supports for thin-layer chromatography are discussed. For reversed-phase supports substance Rf values decrease with the length of the alkyl chain and the degree of modification. Likewise, for a given solvent of constant composition the times required for development become longer. Owing to their pronounced hydrophobic nature reversed-phase supports which have been modified to the maximum extent can only be used with mobile phases having a water content not exceeding approximately 40%. This limitation does not apply, however, to reversed-phase supports having a defined low degree of surface modification.

Similarly, the hydrophilic aminopropyl and cyanopropyl modified plates do not impose any limitations to solvent composition. These medium-polar pre-coated layers can offer a wide range of interactions including ion exchange, adsorption, and hydrophobic interactions.

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Author information

Authors and Affiliations

  1. E. Merck, P. O. box 4119, D-6100, Darmstadt, Germany

    W. Fischer, H. E. Hauck & W. Jost

Authors
  1. W. Fischer
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  2. H. E. Hauck
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  3. W. Jost
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Editor information

Editors and Affiliations

  1. Glaxo Group Research Limited, Ware, UK

    F. A. A. Dallas

  2. BP Research Centre, Sunbury-on-Thames, UK

    H. Read

  3. ICI Pharmaceuticals Division, Macclesfield, UK

    R. J. Ruane  & I. D. Wilson  & 

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© 1988 Springer Science+Business Media New York

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Fischer, W., Hauck, H.E., Jost, W. (1988). New Sorbents for Thin-Layer Chromatography. In: Dallas, F.A.A., Read, H., Ruane, R.J., Wilson, I.D. (eds) Recent Advances in Thin-Layer Chromatography. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-2221-2_15

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  • DOI: https://doi.org/10.1007/978-1-4899-2221-2_15

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4899-2223-6

  • Online ISBN: 978-1-4899-2221-2

  • eBook Packages: Springer Book Archive

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