Abstract
In order to control the maximum levels of As, Cr, Pb, Cd, and Sn in meat products, it is proposed to transfer them to a suspension of 140 mg/mL and use an atomic absorption spectrometer with a graphite furnace, equipped with a probe attachment for a two-stage atomization of the suspension. The working linear range covers 0.2–9 ultimate allowable concentrations. The error is smaller by factors of 2 to 3 than that of the methods with sample dissolution, and it saves at least 12 h in time.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.3103%2FS002713142001006X/MediaObjects/11967_2020_7052_Fig1_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.3103%2FS002713142001006X/MediaObjects/11967_2020_7052_Fig2_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.3103%2FS002713142001006X/MediaObjects/11967_2020_7052_Fig3_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.3103%2FS002713142001006X/MediaObjects/11967_2020_7052_Fig4_HTML.gif)
Similar content being viewed by others
Notes
w/v is the percentage by weight and volume.
v/v is the percentage by volume.
REFERENCES
TR TS (Technical Regulations of the Customs Union) 021/2011: On the Safety of Food Products, Moscow, 2011, no. 880.
Commission Regulation (EC) no. 1881/2006: Setting Maximum Levels for Certain Contaminants in Foodstuffs, Brussels: European Commission, 2006.
GOST (State Standard) 31671-2012: Foodstuffs. Determination of Trace Elements. Preparation of Samples by Pressure Digestion, Moscow, 2014.
Aras, N.K. and Ataman, O.Y., Trace Element Analysis of Food and Diet, Cambridge: R. Soc. Chem., 2006.
GOST (State Standard) R 51301-99: Foodstuffs and Food Raw Materials. Anodic Strip** Voltammetric Methods of Toxic Traces Elements Determination (Cadmium, Lead, Copper and Zinc), Moscow, 2010.
GOST (State Standard) 31628-2012: Foodstuffs and Food Raw Materials. Anodic Strip** Voltammetric Method of Arsenic Mass Concentration Determination, Moscow, 2014.
GOST (State Standard) 33426-2015: Meat and Meat Products. Determination of Lead and Cadmium by Electrothermal Atomic Absorption Spectrometry, Moscow, 2016.
M (Procedure) 04-64-2017: Food Products and Food Raw Materials. Feed and Raw Materials for Their Production. Method for Measuring the Mass Fraction of Cadmium, Arsenic, Tin, Mercury, Lead, Chromium by Atomic Absorption Spectroscopy Using an Atomic Absorption Spectrometers with Electrothermal Atomization MGA-915, MGA-915M, MGA-915MD, and MGA-1000.
Solid Sample Analysis: Direct and Slurry Sampling Using GF-AAS and ETV-ICP, Kurfürst, U., Ed., Berlin: Springer, 1998.
Schlemmer, G. and Radziuk, B., Analytical Graphite Furnace Atomic Absorption Spectrometry: A Laboratory Guide, Bazel: Birkhäuser Basel, 1999.
GOST (State Standard) R 54639-2011: Foodstuffs and Animal Feeding Stuffs. Determination of Mercury by Zeeman Atomic Absorption Spectrometry, Moscow, 2012.
Viñas, P., Pedro-Martínez, M., and Hernández-Cordoba, M., Anal. Chim. Acta, 2000, vol. 412, p. 121.
Nomura, C.S. and Oliveira, P.V., Quim. Nova, 2006, vol. 29, no. 2, p. 234.
Gallindo Borges, D.L., Furtado da Silva, A., Welz, B., Curtius, J., and Heitmann, U., J. Anal. At. Spectrom., 2006, vol. 21, p. 763.
Dami, I.C.F., Silva, M.M., Vale, M.G.R., and Welz, B., Spectrochim. Acta, Part B, 2007, vol. 62, p. 1037.
Welz, B., Becker-Ross, H., Florek, S., and Heitmann, U., High-Resolution Continuum Source AAS: The Better Way to Do Atomic Absorption Spectrometry, Darmstadt: Wiley, 2005.
Zakharov, Yu.A. and Kokorina, O.B., J. Anal. Chem., 2012, vol. 67, no. 8, p. 706. https://doi.org/10.1134/S1061934812080084
Zakharov, Yu.A., Kokorina, O.B., Khasanova, S.I., Irisov, D.S., and Khaibullin, R.R., Analitika Kontrol’, 2013, vol. 17, no. 3, p. 275.
Zakharov, Yu.A., Okunev, R.V., Khaibullin, R.R., Irisov, D.S., and Sadykov, M.F., Zavod. Lab.,Diagn. Mater., 2014, vol. 80, no. 2, p. 12.
Petrov, Yu.F., Gudkov, A.Yu., Bagmanova, N.N., Kuznetsov, V.M., Golovny, I.A., El’kind, O.B., and Sudakov, E.V., Ross. Parazitol. Zh., 2009, vol. 4, p. 86.
Narozhnykh, K.N., Strizhkova, M.V., and Konovalova, T.V., Fundam. Issled. Biol. Nauki, 2015, no. 2, p. 2158.
Frolova, O.A., Karpova, M.V., Makhmutova, I.P., and Musin, R.A., Gig. Sanit., 2014, vol. 93, no. 6, p. 72.
Duta, S., Robouch, P., Barbu, L., and Taylor, P., Spectrochim. Acta, Part A, 2007, no. 62, p. 337. https://doi.org/10.1016/j.sab.2007.02.004
Zakharov, Yu.A., Gil’mutdinov, A.K., and Kokorina, O.B., J. Appl. Spectrosc., 2005, vol. 72, no. 1, p. 132. https://doi.org/10.1007/s10812-005-0043-3
Khaibullin, R.R., Irisov, D.S., Salikhova, O.B., and Zakharov, Yu.A., Opt. Spectrosc., 2019, vol. 126, no. 2, p. 161. https://doi.org/10.1134/S0030400X19020140
ACKNOWLEDGMENTS
The authors thank A. Kh. Gilmutdinov and K.Yu. Nagulin for providing the standard samples of biological tissues.
Funding
This work was supported by Kazan (Volga) Federal University and LLC Atzond.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
CONFLICT OF INTEREST
The authors declare that they have no conflict of interest.
LIST OF ABBREVIATIONS
MPC, maximum permissible concentration; Sr, standard deviation; P, confidence probability
Additional information
Translated by Sh. Galyaltdinov
About this article
Cite this article
Khaibullin, R.R., Irisov, D.S., Zakirov, A.I. et al. Atomic Absorption Control of Ultimate Allowable Concentration of Elements in Meat Products without Sample Dissolution. Moscow Univ. Chem. Bull. 75, 56–63 (2020). https://doi.org/10.3103/S002713142001006X
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S002713142001006X