SpringerLink
Log in

Ordering of the O(2)…D… O(2) bonds near the phase transition in KD3(SeO3)2 single crystals by D nuclear magnetic resonance

  • Research Article
  • Published:
Central European Journal of Physics

Abstract

Deuterium resonance investigations of KD3(SeO3)2 single crystals have been performed near the phase transition temperature T C . There are two types of deuterium bonds in these crystals with different behaviors at this phase transition. Our experimental results show that there are significant changes in the D spinlattice relaxation time T 1 at T C ; the abrupt decrease in T 1 near T C can be explained by the critical slowing down of an overdamped soft pseudospin-type deuteron mode. Further, the ordering of the O(2)…D… O(2) bonds is affected by the phase transition, whereas the ordering of the O(1)-D… O(3) bonds is unaffected. The D NMR measurements also show that the D(2) deuteron disordering above T C is dynamic and not static.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. L.W. Gorbatyi, W.I. Ponomarev, D.M. Kheiker, Kristallografiya 16, 899 (1971)

    Google Scholar 

  2. W. Zapart, S. Waplak, J. Stankowski, L. Shuvalov, J. Phys. Soc. Jpn. 44, 1600 (1978)

    Article  ADS  Google Scholar 

  3. A. Sakai, I. Tatsuzaki, J. Phys. Soc. Jpn. 50, 3016 (1981)

    Article  ADS  Google Scholar 

  4. L.A. Huvalov, N.R. Ivanov, T.K. Sitnik, Kristallografiya 12, 315 (1967)

    Google Scholar 

  5. N.R. Ivanov, L.A. Shuvalov, N.V. Gordeeva, Sov. Phys. Crystallogr. 13, 145 (1968)

    Google Scholar 

  6. T. Yagi, I. Tatsuzaki, J. Phys. Soc. Jpn. 26, 865 (1969)

    Article  ADS  Google Scholar 

  7. Y. Makita, F. Sakurai, T. Osaka, I. Tatsuzaki, J. Phys. Soc. Jpn. 42, 518 (1977)

    Article  ADS  Google Scholar 

  8. S. Grande, H.D. Mecke, L.A. Shuvalov, Phys. Stat. Sol. (a) 46, 547 (1978)

    Article  ADS  Google Scholar 

  9. M. Kasahara, J. Phys. Soc. Jpn. 44, 537 (1978)

    Article  ADS  Google Scholar 

  10. H. Tanaka, T. Yagi, I. Tatsuzaki, J. Phys. Soc. Jpn. 44, 1257 (1978)

    Article  ADS  Google Scholar 

  11. T. Makita, T. Osaka, A. Miyazaki, J. Phys. Soc. Jpn. 44, 225 (1978)

    Article  ADS  Google Scholar 

  12. N.R. Ivanov, Izv. Akad. Nauk SSSR, Ser. Fiz. 43, 1706 (1979)

    Google Scholar 

  13. R. Blinc, B. Lozar, J. Slak, S. Zumer, L.A. Shuvalov, Phys. Rev. B 23, 6133 (1981)

    Article  ADS  Google Scholar 

  14. J. Seliger, V. Zagar, R. Blinc, A. Novak, J. Chem. Phys. 84, 5857 (1986)

    Article  ADS  Google Scholar 

  15. C.W. Garland, G. Park, I. Tatsuzaki, Phys. Rev. B 29, 221 (1984)

    Article  ADS  Google Scholar 

  16. L.W. Gorbatyi, W.I. Ponomarev, D.M. Kheiker, Sov. Phys. Crystallogr. 16, 781 (1972)

    Google Scholar 

  17. F. Hansen, R.G. Hazell, S.E. Rasmussen, Acta Chem. Scand. 23, 2561 (1969)

    Article  Google Scholar 

  18. M.S. Lehmann, F.K. Larsen, Acta Chem. Scand. 25, 3859 (1971)

    Article  Google Scholar 

  19. Y. Iwata, N. Koyano, I. Shibuya, M. Tokunaga, J. Phys. Soc. Jpn. 47, 922 (1979)

    Article  ADS  Google Scholar 

  20. B. Cowan, Nuclear Magnetic Resonance and Relaxation, Cambridge University Press, Cambridge, 1997)

    Book  Google Scholar 

  21. M. Igarashi, H. Kitagawa, S. Takahashi, R. Yoshizak, Y. Abe, Z. Naturforsch 47a, 313 (1992)

    Google Scholar 

  22. G. Bonera, F. Borsa, A. Rigamonti, Phys. Rev. B 21, 2784 (1970)

    Article  ADS  Google Scholar 

  23. S. Towta, D.G. Hughes, J. Phys.: Condens. Matter 2, 2021 (1990)

    Article  ADS  Google Scholar 

  24. O.V. Rozanov, Yu.N. Moskvich, A.A. Sukhovskii, Sov. Phys. Solid State 25, 212 (1983)

    Google Scholar 

  25. A.R. Lim, W.K. Jung, J. Phys. D: Appl. Phys. 41, 135407 (2008)

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Science Education, Jeonju University, Jeonju, 560-759, Korea

    Ae Ran Lim

  2. School of Nanoscience and Technology, Pusan National University, Miryang, 627-706, Korea

    Se-Young Jeong

Authors
  1. Ae Ran Lim
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Se-Young Jeong
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Ae Ran Lim.

About this article

Cite this article

Lim, A.R., Jeong, SY. Ordering of the O(2)…D… O(2) bonds near the phase transition in KD3(SeO3)2 single crystals by D nuclear magnetic resonance. centr.eur.j.phys. 11, 124–129 (2013). https://doi.org/10.2478/s11534-012-0120-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2478/s11534-012-0120-1

Keywords

Search

Navigation