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The Limitations of the Constant Photocurrent Method for Determining Subgap Absorption

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The subgap absorption αcpm measured by the constant photocurrent method (CPM) was studied between 4.2K and 300K for different do**s and defect concentrations N in hydrogenated amorphous silicon (a-Si:H). We found that αcpm is reduced by up to a factor 100 between 50K and 200K due to infrared selfquenching which changes the charge state of the defects and enhances recombination. The effect is diminished at high N and large do**. The relative change Δα/α reflects ΔN/N both at very low and high temperatures. For undoped samples αcpm is about four times larger at 4.2K than at 300K. For doped samples the two values are essentially the same.

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Stradins, P., Fritzsche, H. & Tran, M. The Limitations of the Constant Photocurrent Method for Determining Subgap Absorption. MRS Online Proceedings Library 377, 467–472 (1995). https://doi.org/10.1557/PROC-377-467

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