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Sulfurized Passivation of GaAs(100) Surfaces

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We have developed a new electrochemical passivation method to obtain a quite stable sulfide layer on GaAs surface. This layer is very thick and contains a mixture of Ga, As, S, O and H compounds. The photoluminescence (PL) spectrum of such anodic sulfurized GaAs surface shows big intensity enhancement as compared with that of as-etched GaAs samples; No visual intensity decay occurs under laser beam illumination, which maintains for more than seven months. The structure and composition of the passivation layers are investigated by the X-ray photoelectron spectroscopy and the mechanism of the layer formation is suggested.

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Li, Z.S., Hou, X.Y., Cai, W.Z. et al. Sulfurized Passivation of GaAs(100) Surfaces. MRS Online Proceedings Library 284, 607–612 (1992). https://doi.org/10.1557/PROC-284-607

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  • DOI: https://doi.org/10.1557/PROC-284-607

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