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Performance of Organic Frameworks as Thriving Mild Steel Corrosion Inhibitors in Acid Medium: Syntheses and Characterization

  • PHYSICOCHEMICAL PROBLEMS OF MATERIALS PROTECTION
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Abstract

The study described the synthesis and spectral characterization of four novel enolimine ligands; 1-(((2-hydroxy-5-methylphenyl)imino)methyl)naphthalene-2-ol(L1), N-((2-hydroxynaphthalen-1-yl)methylene)pyrazinen-2-carboxamide(L2), 1-((thiazol-2-ylimino)methyl)naphthalene-2-ol(L3) and 1-(((3-methylpyridin-2-yl)imino)methyl)naphthalene-2-ol(L4) by solubility; melting point and elemental (CHNS) evaluations; proton and carbon nuclear magnetic resonance, electronic (UV–Vis) and vibrational (IR), spectrophotometry. The ligands were investigated for corrosion inhibition potentials. The solubility data revealed that all the organic ligands were soluble in dimethylformamide ((CH3)2SO) but insoluble with water (OH2). The IR spectra of the ligands presented bands at 1631–1685 cm–1 indicative of imine functional group and corroborative of enol assemblage. The effect of the ligands on acid corrosion of mild steel (ms) confirmed substantial corrosion inhibition behaviour as against corrosion of ms in one mole of hydrochloric acid solution. The weight loss (WL) shows that the heterocyclic organic inhibitors had excellent corrosion inhibition performance at high temperature. The highest inhibition efficiency of 90% was observed at 3 h for both L3 and L4, and 89.20% for L3 at 5-h immersion in the acid solution at 308 K temperature, and 500 ppm concentration. Substantial chemical calculations were also accomplished at B3LYP level with 6-31G (d, p) basis set and molecular descriptors which include dipole moment (μ), energy gap, EHOMO, and ELUMO were used. Koopman’s theorem was used to derive and analyze the global reactivity descriptors; global softness (S), global hardness (η), electrophilicity index (ω). The organic ligands were found to be in good agreement with both experimental and theoretical results.

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This work was supported by regular institutional funding, and no additional grants were obtained.

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Authors and Affiliations

  1. Department of Chemistry, Ignatius Ajuru University of Education, Port Harcourt, Rivers State, Nigeria

    Festus Chioma, Wodi Theresa Chizoba & Iyo Isreal Atamunotekeari

  2. Community Boys Senior Secondary, Elelenwo, Port Harcourt, Rivers State, Nigeria

    Wodi Theresa Chizoba

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  1. Festus Chioma
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Correspondence to Festus Chioma.

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Festus Chioma, Chizoba, W.T. & Atamunotekeari, I.I. Performance of Organic Frameworks as Thriving Mild Steel Corrosion Inhibitors in Acid Medium: Syntheses and Characterization. Prot Met Phys Chem Surf 59, 504–515 (2023). https://doi.org/10.1134/S2070205123700594

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