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Specific Features of Dichloroacetic Acid Hydration

  • PHYSICAL METHODS FOR INVESTIGATION OF CHEMICAL REACTIONS
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Abstract

The structure of hydrated ions of dichloroacetic acid (DCA) is established by electrospraying aqueous solutions of DCA into the vacuum chamber of a mass spectrograph. At an acid concentration of 0.01 mol/L, the number of hydrated ions decreases monotonically with an increase in the degree of their hydration. The resulting mass spectrum provides information on the distribution of hydrated ions in solution, which makes the mass spectrographic method of spraying electrolytes in a vacuum applicable for determining the composition of electrolyte solutions in environmental studies.

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Funding

This study was carried out as part of a state assignment of the Ministry of Science and Higher Education of the Russian Federation (topic no. АААА-А20-120021390044-2) and was supported by grant no. 19-05-50076 (Microcosm) from the Russian Foundation for Basic Research.

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Authors and Affiliations

  1. Semenov Federal Research Center of Chemical Physics, Russian Academy of Sciences, Moscow, Russia

    G. V. Karpov, E. S. Vasiliev, N. D. Volkov, I. I. Morozov, O. A. Olkhov, V. L. Shapovalov & D. V. Shestakov

  2. Moscow State University, Moscow, Russia

    S. V. Savilov

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  1. G. V. Karpov
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  2. E. S. Vasiliev
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  3. N. D. Volkov
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  4. I. I. Morozov
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  5. S. V. Savilov
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  6. O. A. Olkhov
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  7. V. L. Shapovalov
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  8. D. V. Shestakov
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Correspondence to I. I. Morozov.

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Karpov, G.V., Vasiliev, E.S., Volkov, N.D. et al. Specific Features of Dichloroacetic Acid Hydration. Russ. J. Phys. Chem. B 14, 829–834 (2020). https://doi.org/10.1134/S1990793120050218

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  • DOI: https://doi.org/10.1134/S1990793120050218

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