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Regioselective synthesis of functional tellanes from tellurium tetrahalides and 1-octene

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Abstract

Proceeding from TeCl4 and 1-octene a regioselective method was developed of the synthesis of trichloro(2-chlorooctyl)tellane. At adding methanol to this compound chlorine was easily replaced at room temperature by a methoxy group affording trichloro(2-methoxyoctyl)tellane. The reaction of TeBr4 with 1-octene in methanol resulted in tribromo(2-methoxyoctyl)tellane. A reduction of trichloro- and tribromo(2-methoxyoctyl)tellanes occurs the most selectively in the system NaBH4–water–THF giving 1,2-bis(2-methoxyoctyl)ditellane. The reactions are characterized by a high selectivity and quantitative yields of the products.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    S. I. Udalova, M. V. Musalova, M. V. Musalov, V. A. Potapov & S. V. Amosova

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  1. S. I. Udalova
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  2. M. V. Musalova
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  3. M. V. Musalov
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  4. V. A. Potapov
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  5. S. V. Amosova
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Corresponding author

Correspondence to S. V. Amosova.

Additional information

Original Russian Text © S.I. Udalova, M.V. Musalova, M.V. Musalov, V.A. Potapov, S.V. Amosova, 2017, published in Zhurnal Organicheskoi Khimii, 2017, Vol. 53, No. 5, pp. 647–650.

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Udalova, S.I., Musalova, M.V., Musalov, M.V. et al. Regioselective synthesis of functional tellanes from tellurium tetrahalides and 1-octene. Russ J Org Chem 53, 652–655 (2017). https://doi.org/10.1134/S1070428017050025

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