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Development of Effective Depressor Additives to Diesel Fuel, Based on Copolymers of Stearyl Methacrylate with Monomers of Various Structures

  • Macromolecular Compounds and Polymeric Materials
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Abstract

Depressor additives based on stearyl methacrylate homopolymer and its copolymers with various monomers (butyl methacrylate, methacrylic acid esters of С10–С14 fraction, maleic anhydride) were synthesized in the presence of reversible addition–fragmentation chain-transfer agents allowing control of the molecular-weight characteristics of the polymers. The low-temperature properties of the diesel fuel containing additives based on the above polymers were evaluated. The copolymers exhibit the better depressor effect compared to the stearyl methacrylate homopolymer. Modification of the stearyl methacrylate–maleic anhydride copolymer with 1-octanol was performed. The modified additive well competes in performance with the modern commercial depressor-dispersing additives and can decrease the congealing point of hydrotreated diesel fuels by 20°С.

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REFERENCES

  1. Speight, J.G., Handbook of Petrochemical Processes, Boca Raton, FL: CRC, 2019.

    Book  Google Scholar 

  2. Danilov, A.M., Petrol. Chem., 2015, vol. 55, pp. 169–179. https://doi.org/10.1134/S0965544115030020

    Article  CAS  Google Scholar 

  3. Grishin, D.F., Petrol. Chem., 2017, vol. 57, no. 10, pp. 813–825. https://doi.org/10.1134/S0965544117100097

    Article  CAS  Google Scholar 

  4. Ivchenko, P.V. and Nifant’ev, I.E., Polym. Sci., Ser. A, 2018, vol. 60, pp. 577–593. https://doi.org/10.1134/S0965545X18050061

    Article  CAS  Google Scholar 

  5. Soldi, R.A., Oliveira, A.R.S., Barbosa, R.V., and César-Oliveira, M.A.F., Eur. Polym. J., 2007, vol. 43, no. 8, pp. 3671–3678. https://doi.org/10.1016/j.eurpolymj.2006.07.021

    Article  CAS  Google Scholar 

  6. Chen, F., Liu, J., Yang, T., Yin, S., **e, M., Dai, B., Han, S., and Xue, Y., Fuel, 2020, vol. 268, pp. 1–8. https://doi.org/10.1016/j.fuel.2020.117392

    Article  CAS  Google Scholar 

  7. Lin, H., **e, M., Yin, S., Yang, T., Su, B., Chen, F., Han, S., and Xue, Y., Energy Fuels, 2020, vol. 34, no. 2, pp. 1514–1523. https://doi.org/10.1021/acs.energyfuels.9b03603

    Article  CAS  Google Scholar 

  8. Yang, T., Wu, J., Yuan, M., Li, X., Yin, S., Su, B., Yan, J., Lin, H., Xue, Y., and Han, S., Fuel, 2021, vol. 290, ID 120035. https://doi.org/10.1016/j.fuel.2020.120035

    Article  CAS  Google Scholar 

  9. Lin, H., Yin, S., Su, B., Xue, Y., and Han, S., Fuel, 2021, vol. 290, ID 120002. https://doi.org/10.1016/j.fuel.2020.120002

    Article  CAS  Google Scholar 

  10. Ren, F., Lu, Y., Sun, B., Wang, C., Yan, J., Lin, H., Xue, Y., and Han, S., Energy, 2022, vol. 25, ID 124438. https://doi.org/10.1016/j.energy.2022.124438

    Article  CAS  Google Scholar 

  11. Pucko, I., Racar, M., and Faraguna, F., Fuel, 2022, vol. 324, ID 124821. https://doi.org/10.1016/j.fuel.2022.124821

    Article  CAS  Google Scholar 

  12. Li, X., Yuan, M., Xue, Y., Lin, H., and Han, S., Colloid Surf. A, 2022, vol. 642, ID 128672. https://doi.org/10.1016/j.colsurfa.2022.128672

    Article  CAS  Google Scholar 

  13. Sun, B., Chen, F., Lin, H., Xue, Y., and Han, S., Colloids Surf. A: Physicochem. Eng. Aspects, 2023, vol. 658, ID 130636. https://doi.org/10.1016/j.colsurfa.2022.130636

    Article  CAS  Google Scholar 

  14. Pavlovskaya, M.V., Kriulichev, I.P., and Grishin, D.F., Russ. J. Appl. Chem., 2020, vol. 93, no. 9, pp. 1332–1339. https://doi.org/10.1134/S1070427220090049

    Article  CAS  Google Scholar 

  15. Simanskaya, K.Y., Grishin, I.D., and Grishin, D.F., Russ. J. Appl. Chem., 2016, vol. 89, no. 7, pp. 1119–1125. https://doi.org/10.1134/S1070427216070119

    Article  CAS  Google Scholar 

  16. Grishin, D.F. and Grishin, I.D., Russ. Chem. Rev., 2021, vol. 90, p. 231. https://doi.org/10.1070/RCR4964

    Article  CAS  Google Scholar 

  17. Semsarilar, M. and Abetz, V., Macromol. Chem. Phys., 2021, vol. 222, no. 1, ID 2000311. https://doi.org/10.1002/macp.202000311

    Article  CAS  Google Scholar 

  18. Tilottama, B., Manojkumar, K., Haribabu, P.M., and Vijayakrishna, K., J. Macromol. Sci., Part A: Pure Appl. Chem., 2022, vol. 59, no. 3, pp. 180–201. https://doi.org/10.1080/10601325.2021.2024076

    Article  CAS  Google Scholar 

  19. Chernikova, E.V. and Sivtsov, E.V., Polym. Sci., Ser. B, 2017, vol. 59, no. 2, pp. 117–146. https://doi.org/10.1134/S1560090417020038

    Article  CAS  Google Scholar 

  20. Perrier, S., Macromolecules, 2017, vol. 50, no. 19, pp. 7433–7447. https://doi.org/10.1021/acs.macromol.7b00767

    Article  CAS  Google Scholar 

  21. Moad, G., Сhong, Y.K., Postma, A., Rizzardo, E., and Thang, S.H., Polymer, 2005, vol. 46, pp. 8458–8468. https://doi.org/10.1016/j.polymer.2004.12.061

    Article  CAS  Google Scholar 

  22. Monomery: Sbornik statei (Monomers: Coll. of Papers), Korshak, V.V., Ed., Moscow: Inostrannaya Literatura, 1951, part 1, p. 138.

  23. Weissberger, A., Proskauer, E., Riddick, J., and Toops, E., Organic Solvents, New York: Interscience, 1955.

    Google Scholar 

  24. Madruga, E.L., Roman, J.S., and Benedi, P., J. Appl. Polym. Sci., 1990, vol. 41, nos. 5–6, pp. 1133–1140.

    Article  CAS  Google Scholar 

  25. Brandrup, J., Immergut, E.H., and Grulke, E.A., Polymer Handbook, New York: Wiley, 1999.

    Google Scholar 

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Funding

This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained.

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Authors and Affiliations

  1. Lobachevsky University, pr. Gagarina 23, 603950, Nizhny Novgorod, Russia

    E. V. Kolyakina, M. V. Pavlovskaya, Yu. S. Pronina, S. D. Zaitsev & D. F. Grishin

Authors
  1. E. V. Kolyakina
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  2. M. V. Pavlovskaya
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  3. Yu. S. Pronina
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  4. S. D. Zaitsev
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  5. D. F. Grishin
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Contributions

E.V. Kolyakina: collection, analysis, and interpretation of the results of experiments on polymerization of monomers in the presence of 2-cyano-2-propyl dithiobenzoate (CPTB), study of the low-temperature characteristics of diesel fuel, manuscript preparation, major contribution to writing the Results and Discussion section, and approval of the final version of the paper; M.V. Pavlovskaya: collection, analysis, and interpretation of the results of experiments on polymerization of monomers in the presence of 2-cyano-2-propyl dodecyl trithiocarbonate (CPTC), study of the low-temperature characteristics of diesel fuel, collection of literature data and preparation of the literature review, and approval of the final version of the paper; Yu.S. Pronina: development and description of the experimental procedures for modifying stearyl methacrylate–maleic anhydride copolymers, analysis of the copolymers by IR and NMR spectroscopy, description of the results, and approval of the final version of the paper; S.D. Zaitsev: synthesis of 2-cyano-2-propyl dodecyl trithiocarbonate, participation in the data processing by critical revision of the results and manuscript, and approval of the final version of the paper; D.F. Grishin: significant contribution to the concept of the study, evaluation and analysis of the results obtained, participation in the data processing by critical revision of the results and manuscript, and approval of the final version of the paper.

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Correspondence to E. V. Kolyakina.

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Translated from Zhurnal Prikladnoi Khimii, No. 10, pp. 809–823, August, 2023 https://www.elibrary.ru/MFMNGY

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Kolyakina, E.V., Pavlovskaya, M.V., Pronina, Y.S. et al. Development of Effective Depressor Additives to Diesel Fuel, Based on Copolymers of Stearyl Methacrylate with Monomers of Various Structures. Russ J Appl Chem 96, 889–902 (2023). https://doi.org/10.1134/S1070427223100026

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