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Mechanochemical Synthesis of Fluorine-Conducting Solid Electrolytes Based on Tysonite and Fluorite Structures

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Abstract

The possibilities of the mechanochemical synthesis of new fluorine-conducting solid electrolytes based on tysonite and fluorite structures were considered. For the first time, solid solutions in the CeF3–SnF2 system with SnF2 content of 5–30 mol % were synthesized. The possibility of stabilizing the structure of fluorite in solid solutions based on lead(II) fluorine under the conditions of mechanochemical synthesis has been demonstrated.

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ACKNOWLEDGMENTS

The equipment of the resource centers of St. Petersburg State University Center for Innovative Technologies of Composite Nanomaterials and “Cryogenic department” was used in the work.

Funding

The work was carried out with financial support from the Russian Science Foundation (grant No. 22-23-00465).

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Authors and Affiliations

  1. St. Petersburg University, 199034, St. Petersburg, Russia

    N. A. Melnikova, Qianlong Ji, Baijun Fei, O. V. Glumov & I. V. Murin

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  1. N. A. Melnikova
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  2. Qianlong Ji
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  3. Baijun Fei
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  4. O. V. Glumov
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Correspondence to N. A. Melnikova.

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To the 300th Anniversary of the founding of St. Petersburg University

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Melnikova, N.A., Ji, Q., Fei, B. et al. Mechanochemical Synthesis of Fluorine-Conducting Solid Electrolytes Based on Tysonite and Fluorite Structures. Russ J Gen Chem 94 (Suppl 1), S28–S35 (2024). https://doi.org/10.1134/S1070363224140044

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