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Ytterbium Complexes with Redox-Active N,N-Chelating Ligands

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Abstract

1,2-Bis[(2,6-dibenzhydryl-4-methylphenyl)imino]acenaphthene (ArBIG-bian) reacts with an excess of ytterbium metal in 1,2-dimethoxyethane (DME) to afford solvent-free ytterbium complex of ArBIG-bian dianion, [(ArBIG-bian)Yb]. The reaction of [(ArBIG-bian)Yb] with 2,2′-bipyridine (bpy) (1 to 2) in DME proceeds with the electron transfer from the metal to the bpy and results in ytterbium(III) derivative [(ArBIG-bian)Yb(bpy)2], containing both neutral and radical-anionic bpy ligands. The newly prepared compounds were characterized by IR, NMR spectroscopy. The molecular structure of [(ArBIG-bian)Yb(bpy)2] was determined by single crystal X-ray analysis.

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Funding

This work was carried out within the state assignment of the Ministry of Science and Higher Education of the Russian Federation using the equipment of the Center for Collective Use “Analytical Center of the IOMC RAS” with the financial support of the grant “Ensuring the development of the material and technical infrastructure of the centers for collective use of scientific equipmen” (unique identifier RF-2296.61321X0017, agreement number 075-15-2021-670).

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Authors and Affiliations

  1. G.A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences, 603950, Nizhny Novgorod, Russia

    D. A. Lukina, A. A. Skatova, E. A. Kozlova & I. L. Fedushkin

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  1. D. A. Lukina
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  2. A. A. Skatova
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  3. E. A. Kozlova
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  4. I. L. Fedushkin
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Correspondence to I. L. Fedushkin.

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I.L. Fedushkin is a member of the Editorial Board of the Russian Journal of General Chemistry. The remaining authors declare no conflict of interest.

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To the 35th Anniversary of the founding of the G.A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

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Lukina, D.A., Skatova, A.A., Kozlova, E.A. et al. Ytterbium Complexes with Redox-Active N,N-Chelating Ligands. Russ J Gen Chem 93 (Suppl 3), S782–S787 (2023). https://doi.org/10.1134/S1070363223160168

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