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A New Biocompatible Metal-Organic Framework Prepared by Green Chemistry Methods

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Abstract

A new biocompatible metal-organic framework [Mg(Mal)(H2O)](H2O) (H2Mal = malic acid) (I) was synthesized under solvothermal conditions, isolated in a pure state, and characterized by elemental analysis and X-ray diffraction. Compound I, which is the second example of a magnesium metal-organic framework based on malic acid, was prepared under drastic conditions of solvothermal synthesis. Cysteine or products of its decomposition were found to have a template effect on the formation of malic acid-based metal-organic frameworks under the chosen drastic conditions.

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ACKNOWLEDGMENTS

Elemental analysis was carried out using research equipment of the Center for Molecular Structure Investigation, Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, under the support of the Ministry of Science and Higher Education of the Russian Federation.

Funding

This study was supported by the Russian Science Foundation (grant no. 20-73-10200).

Author information

Authors and Affiliations

  1. Moscow Institute of Physics and Technology (National Research University), Moscow, Russia

    E. A. Mayorova, A. M. Pak & V. V. Novikov

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

    A. M. Pak, Yu. V. Nelyubina & V. V. Novikov

  3. Bauman Moscow State Technical University, Moscow, Russia

    Yu. V. Nelyubina & V. V. Novikov

Authors
  1. E. A. Mayorova
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  2. A. M. Pak
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  3. Yu. V. Nelyubina
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  4. V. V. Novikov
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Corresponding author

Correspondence to V. V. Novikov.

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Translated by Z. Svitanko

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Mayorova, E.A., Pak, A.M., Nelyubina, Y.V. et al. A New Biocompatible Metal-Organic Framework Prepared by Green Chemistry Methods. Russ J Coord Chem 49, 142–147 (2023). https://doi.org/10.1134/S1070328423700422

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  • DOI: https://doi.org/10.1134/S1070328423700422

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