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Complexes [Fe2(μ-S2ER2)(CO)6] (E = Si, Sn) as Reagents for the Synthesis of Heterometallic Clusters: Synthesis, Structure, and Reactions with Halogen-Containing Metal Complexes

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Abstract

Binuclear complexes [Fe2(µ-S2ER2)(CO)6] (ER2 = SiMe2 (Iа), SiEt2 (Ib), SnEt2 (Ic)), promising precursors of heterometallic clusters, were synthesized. Reactions of these complexes with transition metal halide complexes, [Cp"RhCl2]2 (Cp" = η5-C5H3tBu2), [(Dppe)NiCl2] (Dppe = Ph2PCH2CH2PPh2), [(Ph3P)AuCl], and [Mn(CO)5Cl], were studied. The reactions gave heterometallic clusters [Fe2Rh(µ3-S)2(CO)6Cp"] (II), [Fe2Ni(µ3-S)2(CO)6(Dppe)] (III), [Fe2(CO)6(µ-SSnClEt2)(µ-SAu(PPh3))] (IV), [Fe2(CO)6(µ4,η2-S2SnEt2){Mn(CO)4Cl}2] (V), and [Fe2Mn(CO)9Mn(CO)5(µ3-S)(µ4-S)] (VI). Cluster V was found to be converted to VI upon photochemical activation. The structures of compounds I–VI were determined by X-ray diffraction (CIF file CCDC nos. 751214 (Ic), 751215 (III·0.5C7H8), 2062206 (V), 2062207 (Ib), 2062208 (Ia), 2062209 (IV·0.5CH3C5H9).

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ACKNOWLEDGMENTS

The study was carried out within the state assignment for the Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, in the field of fundamental scientific research.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    M. A. Ogienko, N. A. Pushkarevskii, D. A. Bashirov, N. V. Kurat’eva, A. V. Virovets & S. N. Konchenko

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  1. M. A. Ogienko
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  2. N. A. Pushkarevskii
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  3. D. A. Bashirov
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  4. N. V. Kurat’eva
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  5. A. V. Virovets
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  6. S. N. Konchenko
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Correspondence to S. N. Konchenko.

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Dedicated to the memory of Professor A.A. Pasynskii

Translated by Z. Svitanko

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Ogienko, M.A., Pushkarevskii, N.A., Bashirov, D.A. et al. Complexes [Fe2(μ-S2ER2)(CO)6] (E = Si, Sn) as Reagents for the Synthesis of Heterometallic Clusters: Synthesis, Structure, and Reactions with Halogen-Containing Metal Complexes. Russ J Coord Chem 47, 567–577 (2021). https://doi.org/10.1134/S1070328421080042

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