Abstract
The specific heat was measured in the range 0.4–300 K in YFe3(BO3)4, Y0.5Gd0.5Fe3(BO3)4, and GdFe3(BO3)4 single crystals. Sharp anomalies were found at temperatures of first-order structural, second-order antiferromagnetic, and first-order spin-reorientational transitions. A Néel temperature of about 37 K was found to be virtually independent of presence of rare-earth ions, indicating rather weak coupling of Gd and Fe subsystems. The contribution of the magnetic system to specific heat was separated through the scaling procedure allowing determination of the magnetic entropy of Fe and Gd subsystems. At the lowest temperatures, the specific heat in GdFe3(BO3)4 exhibits a Schottky-type anomaly, which is due to Gd3+ eightfold degenerate ground-level splitting by the internal magnetic field of the Fe subsystem of about 7 T.
Similar content being viewed by others
References
D. A. Keszler, Curr. Opin. Solid State Mater. Sci. 1, 204 (1996).
C. Cascales, C. Zaldo, U. Caldino, et al., J. Phys.: Condens. Matter 13, 8071 (2001).
A. K. Zvezdin and A. P. Pyatakov, Phys. Usp. 47, 416 (2004).
Y. Fey, B. Lorenz, A. N. Vasiliev, et al., in Abstract of APS March Meeting (Los Angeles, CA, 2005).
A. K. Zvezdin, S. S. Krotov, A. M. Kadomtseva, et al., JETP Lett. 81, 272 (2005).
J. A. Campa, C. Cascales, E. Gutierres-Puebla, et al., Chem. Mater. 9, 237 (1997).
Y. Hinatsu, Y. Doi, K. Ito, et al., J. Solid State Chem. 172, 438 (2003).
R. Z. Levitin, E. A. Popova, R. M. Chtsherbov, et al., JETP Lett. 79, 531 (2004).
L. N. Bezmaternykh, S. A. Kharlamova, and V. L. Temerov, Crystallogr. Rep. 49, 855 (2004).
A. D. Balaev, L. N. Bezmaternykh, I. A. Gudim, et al., J. Magn. Magn. Mater. 258–259, 532 (2003).
Author information
Authors and Affiliations
Additional information
The text was submitted by the authors in English.
Rights and permissions
About this article
Cite this article
Vasiliev, A.N., Popova, E.A., Bezmaternykh, L.N. et al. Specific heat of YFe3(BO3)4, Y0.5Gd0.5Fe3(BO3)4, and GdFe3(BO3)4 . J. Exp. Theor. Phys. 102, 262–265 (2006). https://doi.org/10.1134/S1063776106020075
Received:
Issue Date:
DOI: https://doi.org/10.1134/S1063776106020075