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Magnetically Induced Effects in Ferroelectric Triglycine Sulfate Crystals with Chromium Impurity

  • PHYSICAL PROPERTIES OF CRYSTALS
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Abstract

The influence of a permanent magnetic field on macro- and nanoscopic properties of triglycine sulfate (TGS) crystals with impurity chromium (TGS-Cr) has been investigated. This work continues the previous studies of magnetically induced effects in ferroelectrics. A specific feature of TGS crystals is the presence of a nanoscale relief on a polar (010) cleavage; this nanorelief is a qualitative characteristic of the crystal defect structure. It is shown that the exposure of a crystal in a magnetic field of 2 T leads to a change in its dielectric properties, accompanied by a long-term transformation of the nanorelief. The results obtained are indicative of a magnetically induced change in the defect crystal structure. A qualitative difference is found between the magnetically induced effects in TGS-Cr crystals and undoped TGS crystals. The relationship between the magnetically induced effects and structural defects is discussed.

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ACKNOWLEDGMENTS

We are grateful to V.B. Kvartalov for determining the concentration of Cr3+ in TGS-Cr samples by mass spectrometry.

The experiments were performed using the equipment of the Shared Research Center FSRC “Crystallography and Photonics.”

Funding

This study was supported by the Ministry of Science and Higher Education of the Russian Federation within the State assignment for the Federal Scientific Research Centre “Crystallography and Photonics” of the Russian Academy of Sciences.

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Authors and Affiliations

  1. Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,” Russian Academy of Sciences, 119333, Moscow, Russia

    E. S. Ivanova, E. A. Petrzhik, A. P. Eremeev, R. V. Gainutdinov, A. K. Lashkova, A. G. Ivanova & T. R. Volk

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  1. E. S. Ivanova
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  2. E. A. Petrzhik
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  3. A. P. Eremeev
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  4. R. V. Gainutdinov
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  5. A. K. Lashkova
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  6. A. G. Ivanova
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  7. T. R. Volk
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Correspondence to E. S. Ivanova.

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Dedicated to the memory of L.A. Shuvalov

Translated by Yu. Sin’kov

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Ivanova, E.S., Petrzhik, E.A., Eremeev, A.P. et al. Magnetically Induced Effects in Ferroelectric Triglycine Sulfate Crystals with Chromium Impurity. Crystallogr. Rep. 68, 716–724 (2023). https://doi.org/10.1134/S1063774523700347

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  • DOI: https://doi.org/10.1134/S1063774523700347

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